μ-oxo-bis[(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)]

Base Information

• Chemical Name: μ-oxo-bis[(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)]
• CAS No.: 39393-88-9
• Molecular Formula: C₇₂H₈₈Fe₂N₈O
• Molecular Weight: 1193.24
• Mol file: 39393-88-9.mol

Synonyms:μ-oxo-bis[(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)]

Chemical Property of μ-oxo-bis[(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of μ-oxo-bis[(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)]

There total 5 articles about μ-oxo-bis[(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(2,3,7,8,12,13,17,18-tetraethylporphyrinato)Fe(III)(C6H5) (83614-06-6) → biphenyl (92-52-4,1594-86-1) + μ-oxo-bis[(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)] (39393-88-9)

Guidance literature:

With O₂; In benzene; O2 introduced for 5 min; pptd. (pentane), crystd. (CH2Cl2/MeOH);

DOI:10.1016/S0022-328X(00)85854-4

Reference yield:

iron(III)octaethylporphyrin chloride (28755-93-3) → μ-oxo-bis[(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)] (39393-88-9)

Guidance literature:

With potassium hydroxide; In dichloromethane; stirred overnight under Ar or N2; org. layer was washed with distd. water to neutral, dried over anhyd. Na2SO4, filtered, solvent removed in vac., chromy. of CH2Cl2 soln. on basic alumina, dryness under vac., residue was dissolved in C6H6, soln. waslyophilized;

DOI:10.1021/ja00406a018

Reference yield:

iron(III)octaethylporphyrin chloride (28755-93-3) + sodium hydroxide (1310-73-2) → μ-oxo-bis[(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)] (39393-88-9)

Guidance literature:

In dichloromethane; water;

upstream raw materials:

iron(III)octaethylporphyrin chloride

(2,3,7,8,12,13,17,18-tetraethylporphyrinato)Fe(III)(C₆H₅)

sodium hydroxide

Downstream raw materials:

[Fe(2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphyrinato)(2,6-bis(trifluoroacetylamino)phenolato)]

(2,4,6-trimethylthiophenolato)(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)

(thiophenolato)(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III)

Fe(III)(OEP)(4-tBu-Hcat)