(CO)4W(P(C₆H₅)2)2W(CO)3(C(OCH₃)CH₃)*0.5C₄H₈O

Base Information

Chemical Name:(CO)4W(P(C₆H₅)2)2W(CO)3(C(OCH₃)CH₃)*0.5C₄H₈O
CAS No.:89828-41-1
Molecular Formula:0C₄H₈O*C₃₄H₂₆O₈P₂W₂
Molecular Weight:1028.28
Hs Code.:

(CO)4W(P(C<sub>6</sub>H<sub>5</sub>)2)2W(CO)3(C(OCH<sub>3</sub>)CH<sub>3</sub>)*0.5C<sub>4</sub>H<sub>8</sub>O

Synonyms:(CO)4W(P(C₆H₅)2)2W(CO)3(C(OCH₃)CH₃)*0.5C₄H₈O

Suppliers and Price of (CO)4W(P(C₆H₅)2)2W(CO)3(C(OCH₃)CH₃)*0.5C₄H₈O

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (CO)4W(P(C₆H₅)2)2W(CO)3(C(OCH₃)CH₃)*0.5C₄H₈O

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (CO)4W(P(C₆H₅)2)2W(CO)3(C(OCH₃)CH₃)*0.5C₄H₈O

There total 2 articles about (CO)4W(P(C₆H₅)2)2W(CO)3(C(OCH₃)CH₃)*0.5C₄H₈O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: W2(CO)8(μ-PPh2)2

: 917-54-4
methyllithium

: 420-37-1
trimethoxonium tetrafluoroborate

: 89828-41-1
(CO)4W(P(C₆H₅)2)2W(CO)3(C(OCH₃)CH₃)*0.5C₄H₈O

Guidance literature:: In tetrahydrofuran; nitromethane; formation of Li((CO)4W(μ-P(C6H5)2)2W(CO)3(C(O)CH3))*3C4H8O from W2(CO)8(μ-P(C6H5)2)2 and CH3Li in THF and freeing of the solvent; addn. of (CH3)3OBF4; addn. of nitromethane; stirring for a few minutes; removing of the solvent;; extraction with THF; filtration through activated alumina; evaporation of the solvent; elem. anal.;;
DOI:10.1021/ja00246a018

Reference yield:

: 80049-81-6
2K⁽¹⁺⁾*{W₂(CO)8(P(C₆H₅)2)2}^(2-)*2C₄H₈O=K₂{W₂(CO)8(P(C₆H₅)2)2}*2C₄H₈O

: 420-37-1
trimethoxonium tetrafluoroborate

: W2(CO)8(μ-PPh2)2

: 89828-41-1
(CO)4W(P(C₆H₅)2)2W(CO)3(C(OCH₃)CH₃)*0.5C₄H₈O

Guidance literature:: In nitromethane; addn. of CH3NO2 to a mixture of K2(W2(CO)8(μ-P(C6H5)2)2)*2THF and (CH3)3OBF4 with stirring; removing of solvent;; extraction with THF; filtration of the extract; concn.; detn. by 31P(1H) NMR spectroscopy; not isolated;;
DOI:10.1021/ja00246a018