(E)-2-(3'-[(tert-butyldimethylsilyl)oxy]-3'-cyclohexyl-1'-propenyl)-4,5-dimethyl-1,3,2-dioxaborolane

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Chemical Name:(E)-2-(3'-[(tert-butyldimethylsilyl)oxy]-3'-cyclohexyl-1'-propenyl)-4,5-dimethyl-1,3,2-dioxaborolane
CAS No.:203319-90-8
Molecular Formula:C₁₉H₃₇BO₃Si
Molecular Weight:352.397
Hs Code.:

Synonyms:(E)-2-(3'-[(tert-butyldimethylsilyl)oxy]-3'-cyclohexyl-1'-propenyl)-4,5-dimethyl-1,3,2-dioxaborolane

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Chemical Property of (E)-2-(3'-[(tert-butyldimethylsilyl)oxy]-3'-cyclohexyl-1'-propenyl)-4,5-dimethyl-1,3,2-dioxaborolane

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Technology Process of (E)-2-(3'-[(tert-butyldimethylsilyl)oxy]-3'-cyclohexyl-1'-propenyl)-4,5-dimethyl-1,3,2-dioxaborolane

There total 2 articles about (E)-2-(3'-[(tert-butyldimethylsilyl)oxy]-3'-cyclohexyl-1'-propenyl)-4,5-dimethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₅H₃₁BO₃Si

: 513-85-9
2.3-butanediol

: 203319-90-8
(E)-2-(3'-[(tert-butyldimethylsilyl)oxy]-3'-cyclohexyl-1'-propenyl)-4,5-dimethyl-1,3,2-dioxaborolane

Guidance literature:: With magnesium sulfate; Yield given;
DOI:10.1016/S0040-4039(97)10655-4

Reference yield:

: 203301-66-0
tert-Butyl-((E)-1-cyclohexyl-3-iodo-allyloxy)-dimethyl-silane

: 203319-90-8
(E)-2-(3'-[(tert-butyldimethylsilyl)oxy]-3'-cyclohexyl-1'-propenyl)-4,5-dimethyl-1,3,2-dioxaborolane

Guidance literature:: Multi-step reaction with 2 steps

1.1: bipyridine; n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: B(O-i-Pr)3 / tetrahydrofuran; hexane / 4 h / -78 - 20 °C

2.1: 701 mg / MgSO₄ / benzene / 20 °C

With n-butyllithium; 1,1'-bipyridyl; magnesium sulfate; In tetrahydrofuran; hexane; benzene;
DOI:10.1021/jo020375y

Reference yield:

: 61740-26-9
cis-3-acetoxy-5-hydroxycyclopent-1-ene

: 203319-90-8
(E)-2-(3'-[(tert-butyldimethylsilyl)oxy]-3'-cyclohexyl-1'-propenyl)-4,5-dimethyl-1,3,2-dioxaborolane

: (1R,2S)-2-[(E)-3-(tert-Butyl-dimethyl-silanyloxy)-3-cyclohexyl-propenyl]-cyclopent-3-enol

: (1S*,4S*,1'E)-4-[{3'-(tert-butyldimethylsilyl)oxy}-3'-cyclohexyl-1'-propenyl]-2-cyclopenten-1-ol

Guidance literature:: (E)-2-(3'-[(tert-butyldimethylsilyl)oxy]-3'-cyclohexyl-1'-propenyl)-4,5-dimethyl-1,3,2-dioxaborolane; With bis(triphenylphosphine)nickel(II) chloride; n-butyllithium; sodium iodide; In tetrahydrofuran; hexane; Cooling;

cis-3-acetoxy-5-hydroxycyclopent-1-ene; With tert-butyl isocyanide; In tetrahydrofuran; hexane; at 20 ℃; Further stages.;
DOI:10.1021/jo020375y