(Z/E)-6-(8-phenylocta-1,7-diyn-1-yl)-2-[2-(benzo[c]phenanthrene-2-yl)vinyl]pyridine

Base Information

• Chemical Name: (Z/E)-6-(8-phenylocta-1,7-diyn-1-yl)-2-[2-(benzo[c]phenanthrene-2-yl)vinyl]pyridine
• CAS No.: 1130348-23-0
• Molecular Formula: C₃₉H₂₉N
• Molecular Weight: 511.666
• Mol file: 1130348-23-0.mol

Synonyms:(Z/E)-6-(8-phenylocta-1,7-diyn-1-yl)-2-[2-(benzo[c]phenanthrene-2-yl)vinyl]pyridine

Chemical Property of (Z/E)-6-(8-phenylocta-1,7-diyn-1-yl)-2-[2-(benzo[c]phenanthrene-2-yl)vinyl]pyridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z/E)-6-(8-phenylocta-1,7-diyn-1-yl)-2-[2-(benzo[c]phenanthrene-2-yl)vinyl]pyridine

There total 1 articles about (Z/E)-6-(8-phenylocta-1,7-diyn-1-yl)-2-[2-(benzo[c]phenanthrene-2-yl)vinyl]pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

6-(8-phenylocta-1,7-diyn-1-yl)pyridine-2-carboxaldehyde (1130348-21-8) + (benzo[g]phenanthren-3-ylmethyl)triphenylphosphonium bromide (35160-98-6) → (Z/E)-6-(8-phenylocta-1,7-diyn-1-yl)-2-[2-(benzo[c]phenanthrene-2-yl)vinyl]pyridine (1130348-23-0)

Guidance literature:

(benzo[g]phenanthren-3-ylmethyl)triphenylphosphonium bromide; With n-butyllithium; In tetrahydrofuran; Inert atmosphere;

6-(8-phenylocta-1,7-diyn-1-yl)pyridine-2-carboxaldehyde; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1002/chem.200903234

Reference yield: 48.0%

(Z/E)-6-(8-phenylocta-1,7-diyn-1-yl)-2-[2-(benzo[c]phenanthrene-2-yl)vinyl]pyridine (1130348-23-0) → 3-(8-phenylocta-1,7-diyn-1-yl)-4-aza[6]helicene (1130348-19-4,1131286-16-2,1131286-43-5)

Guidance literature:

With iodine; In toluene; UV-irradiation; Inert atmosphere;

DOI:10.1021/ja809396f

upstream raw materials:

6-(8-phenylocta-1,7-diyn-1-yl)pyridine-2-carboxaldehyde

(benzo[g]phenanthren-3-ylmethyl)triphenylphosphonium bromide

Downstream raw materials:

3-(8-phenylocta-1,7-diyn-1-yl)-4-aza[6]helicene