Diphenylphosphinic azide

Base Information

Chemical Name:Diphenylphosphinic azide
CAS No.:4129-17-3
Molecular Formula:C12H11N3OP+
Molecular Weight:243.205
Hs Code.:
NSC Number:76046
DSSTox Substance ID:DTXSID40194275
Nikkaji Number:J50.263D
Wikidata:Q110146672
Mol file:4129-17-3.mol

Synonyms:diphenyl phosphoryl azide;diphenylphosphorazidate;diphenylphosphoryl azide

Suppliers and Price of Diphenylphosphinic azide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
DIPHENYLPHOSPHINYL AZIDE 95.00%
5MG
$ 499.79

Total 6 raw suppliers

Chemical Property of Diphenylphosphinic azide

Chemical Property:

Boiling Point:137-140 °C(Press: 0.05 Torr)
PSA：76.63000
Density:1.2374 g/cm3
LogP:2.67856
XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:243.05614895
Heavy Atom Count:17
Complexity:318

Purity/Quality:

99% ^*data from raw suppliers

DIPHENYLPHOSPHINYL AZIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(=O)(C2=CC=CC=C2)N=[N+]=[N-]

Technology Process of Diphenylphosphinic azide

There total 5 articles about Diphenylphosphinic azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1499-21-4
Diphenylphosphinic chloride

: 4129-17-3
diphenylphosphoranyl azide

Guidance literature:: With sodium azide; In acetonitrile; at 23 ℃; for 12h;
DOI:10.1021/ja062355+

Reference yield: 5.0%

: N-hydroxy succinimide (NHS) ester

: 4129-17-3
diphenylphosphoranyl azide

Guidance literature:

Reference yield:

: 1707-03-5
diphenyl-phosphinic acid

: 4129-17-3
diphenylphosphoranyl azide

Guidance literature:: Multi-step reaction with 2 steps

1: SOCl₂ / 2 h / Heating

2: 90 percent / sodium azide / acetonitrile / 16 h / Ambient temperature

With thionyl chloride; sodium azide; In acetonitrile;
DOI:10.1016/0040-4020(82)80240-8