2-(aminoethyl)-1,4-dimethyl-6-phenylsulphonyloxyfluorene

Base Information

Chemical Name:2-(aminoethyl)-1,4-dimethyl-6-phenylsulphonyloxyfluorene
CAS No.:120931-57-9
Molecular Formula:C₂₃H₂₃NO₃S
Molecular Weight:393.507
Hs Code.:

Synonyms:2-(aminoethyl)-1,4-dimethyl-6-phenylsulphonyloxyfluorene

Suppliers and Price of 2-(aminoethyl)-1,4-dimethyl-6-phenylsulphonyloxyfluorene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(aminoethyl)-1,4-dimethyl-6-phenylsulphonyloxyfluorene

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 2-(aminoethyl)-1,4-dimethyl-6-phenylsulphonyloxyfluorene

There total 12 articles about 2-(aminoethyl)-1,4-dimethyl-6-phenylsulphonyloxyfluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 120931-56-8
2-cyanomethyl-1,4-dimethyl-6-phenylsulphonyloxyfluorene

: 120931-57-9
2-(aminoethyl)-1,4-dimethyl-6-phenylsulphonyloxyfluorene

Guidance literature:: With borane-THF; In tetrahydrofuran; at 80 - 90 ℃; for 24h;

Reference yield:

: 5111-70-6
5-methoxy-1-indanone

: 120931-57-9
2-(aminoethyl)-1,4-dimethyl-6-phenylsulphonyloxyfluorene

Guidance literature:: Multi-step reaction with 12 steps

1: 70 percent / N-bromosuccinimide, benzoyl peroxide / CCl₄ / 3 h / Heating; Irradiation

2: 85 percent / 1,8-diazabicyclo<5.4.0>undec-7-ene / tetrahydrofuran / 0.17 h / -10 °C

3: 79 percent / BF₃*Et₂O / CH₂Cl₂ / 16 h / -78 deg C to r.t.

4: 91 percent / LiAlH₄ / diethyl ether / 0.5 h / Heating

5: 78 percent / 5M H₂SO₄ / tetrahydrofuran / 2 h / Heating

6: 84 percent / 10percent Pd/C / bis-(2-methoxy-ethyl) ether / 6 h / Heating

7: 73 percent / 99percent NH₂NH₂*H₂O / ethane-1,2-diol / 4 h / Heating

8: 3 g / pyridinium hydrochloride / 2 h / 220 °C

9: 75 percent / pyridine / 1.) 0 deg C to r.t., 16 h; 2.) 50 deg C, 3 h

10: 91 percent / conc. HCl / acetic acid; H₂O / 4.5 h / 80 °C

11: 90 percent / dimethylsulfoxide / 0.5 h / Ambient temperature

12: 56 percent / 1M BH₃*THF / tetrahydrofuran / 24 h / 80 - 90 °C

With pyridine; hydrogenchloride; N-Bromosuccinimide; lithium aluminium tetrahydride; Perbenzoic acid; borane-THF; sulfuric acid; boron trifluoride diethyl etherate; pyridine hydrochloride; hydrazine hydrate; 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium on activated charcoal; In tetrahydrofuran; tetrachloromethane; diethyl ether; dichloromethane; diethylene glycol dimethyl ether; water; ethylene glycol; acetic acid; dimethyl sulfoxide;

Reference yield:

: 79827-91-1
3-bromo-5-methoxyindan-1-one

: 120931-57-9
2-(aminoethyl)-1,4-dimethyl-6-phenylsulphonyloxyfluorene

Guidance literature:: Multi-step reaction with 11 steps

1: 85 percent / 1,8-diazabicyclo<5.4.0>undec-7-ene / tetrahydrofuran / 0.17 h / -10 °C

2: 79 percent / BF₃*Et₂O / CH₂Cl₂ / 16 h / -78 deg C to r.t.

3: 91 percent / LiAlH₄ / diethyl ether / 0.5 h / Heating

4: 78 percent / 5M H₂SO₄ / tetrahydrofuran / 2 h / Heating

5: 84 percent / 10percent Pd/C / bis-(2-methoxy-ethyl) ether / 6 h / Heating

6: 73 percent / 99percent NH₂NH₂*H₂O / ethane-1,2-diol / 4 h / Heating

7: 3 g / pyridinium hydrochloride / 2 h / 220 °C

8: 75 percent / pyridine / 1.) 0 deg C to r.t., 16 h; 2.) 50 deg C, 3 h

9: 91 percent / conc. HCl / acetic acid; H₂O / 4.5 h / 80 °C

10: 90 percent / dimethylsulfoxide / 0.5 h / Ambient temperature

11: 56 percent / 1M BH₃*THF / tetrahydrofuran / 24 h / 80 - 90 °C

With pyridine; hydrogenchloride; lithium aluminium tetrahydride; borane-THF; sulfuric acid; boron trifluoride diethyl etherate; pyridine hydrochloride; hydrazine hydrate; 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; dichloromethane; diethylene glycol dimethyl ether; water; ethylene glycol; acetic acid; dimethyl sulfoxide;