1-(4-oxacyclohex-2-enyl)-1,3-diphenylindene

Base Information

• Chemical Name: 1-(4-oxacyclohex-2-enyl)-1,3-diphenylindene
• CAS No.: 345941-52-8
• Molecular Formula: C₂₆H₂₂O
• Molecular Weight: 350.46
• Mol file: 345941-52-8.mol

Synonyms:1-(4-oxacyclohex-2-enyl)-1,3-diphenylindene

Chemical Property of 1-(4-oxacyclohex-2-enyl)-1,3-diphenylindene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 1-(4-oxacyclohex-2-enyl)-1,3-diphenylindene

There total 3 articles about 1-(4-oxacyclohex-2-enyl)-1,3-diphenylindene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.0%

3,4-dihydro-2H-pyran (110-87-2) + 2-chloro-1,3-diphenylindene (33027-38-2) → 1,3-diphenylindene (4467-88-3) + 1-(4-oxacyclohex-2-enyl)-1,3-diphenylindene (345941-52-8)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; for 2.5h; Ambient temperature; Irradiation;

DOI:10.1021/ja00331a023

Reference yield:

3,4-dihydro-2H-pyran (110-87-2) → 1-(4-oxacyclohex-2-enyl)-1,3-diphenylindene (345941-52-8)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; Yield given; Irradiation;

DOI:10.1021/ja00379a050

Reference yield:

2-bromo-1,3-diphenyl-1H-indene (91280-83-0) → 1-(4-oxacyclohex-2-enyl)-1,3-diphenylindene (345941-52-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 15 percent / potassium tert-butoxide, potassium chloride / 1 h / Irradiation

2: 15 percent / potassium tert-butoxide / dimethylsulfoxide / 2.5 h / Ambient temperature; Irradiation

With potassium chloride; potassium tert-butylate; In dimethyl sulfoxide;

DOI:10.1021/ja00331a023

upstream raw materials:

3,4-dihydro-2H-pyran

2-chloro-1,3-diphenylindene

2-bromo-1,3-diphenyl-1H-indene