C₁₈H₂₃N

Base Information

• Chemical Name: C₁₈H₂₃N
• CAS No.: 1646540-74-0
• Molecular Formula: C₁₈H₂₃N
• Molecular Weight: 253.387
• Mol file: 1646540-74-0.mol

Synonyms:C₁₈H₂₃N

Chemical Property of C₁₈H₂₃N

Chemical Property:

Purity/Quality:

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• Pictogram(s):  
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MSDS Files:

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Technology Process of C₁₈H₂₃N

There total 6 articles about C₁₈H₂₃N which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

(E)-N-((1-(phenylethynyl)cyclohexyl)methylene)propan-1-amine → C18H23N (1646540-74-0)

Guidance literature:

With dodecacarbonyl-triangulo-triruthenium; In toluene; at 100 ℃; for 10h; chemoselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201405215

Reference yield:

(1-(2-phenylethynyl)cyclohexyl)methanol (1033621-88-3) → C18H23N (1646540-74-0)

Guidance literature:

Multi-step reaction with 3 steps

1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 20 °C

2: magnesium sulfate / dichloromethane / 50 °C / Sealed tube; Inert atmosphere

3: dodecacarbonyl-triangulo-triruthenium / toluene / 10 h / 100 °C / Inert atmosphere; Schlenk technique

With dodecacarbonyl-triangulo-triruthenium; magnesium sulfate; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In dichloromethane; dimethyl sulfoxide; toluene;

DOI:10.1002/anie.201405215

Reference yield:

1-(2-phenylethynyl)cyclohexanecarbaldehyde (1033621-89-4) → C18H23N (1646540-74-0)

Guidance literature:

Multi-step reaction with 2 steps

1: magnesium sulfate / dichloromethane / 50 °C / Sealed tube; Inert atmosphere

2: dodecacarbonyl-triangulo-triruthenium / toluene / 10 h / 100 °C / Inert atmosphere; Schlenk technique

With dodecacarbonyl-triangulo-triruthenium; magnesium sulfate; In dichloromethane; toluene;

DOI:10.1002/anie.201405215

upstream raw materials:

methyl cyclohexylcarboxylate

methyl 1-(2-phenylethynyl)cyclohexanecarboxylate

(1-(2-phenylethynyl)cyclohexyl)methanol

1-(2-phenylethynyl)cyclohexanecarbaldehyde