(+/-)-5-(p-methoxyphenyl)-4-methyl-3-(2-phenylpent-4-en-1-yloxy)-thiazole-2(3H)-thione

Base Information

Chemical Name:(+/-)-5-(p-methoxyphenyl)-4-methyl-3-(2-phenylpent-4-en-1-yloxy)-thiazole-2(3H)-thione
CAS No.:902757-41-9
Molecular Formula:C₂₂H₂₃NO₂S₂
Molecular Weight:397.562
Hs Code.:

Synonyms:(+/-)-5-(p-methoxyphenyl)-4-methyl-3-(2-phenylpent-4-en-1-yloxy)-thiazole-2(3H)-thione

Suppliers and Price of (+/-)-5-(p-methoxyphenyl)-4-methyl-3-(2-phenylpent-4-en-1-yloxy)-thiazole-2(3H)-thione

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+/-)-5-(p-methoxyphenyl)-4-methyl-3-(2-phenylpent-4-en-1-yloxy)-thiazole-2(3H)-thione

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Technology Process of (+/-)-5-(p-methoxyphenyl)-4-methyl-3-(2-phenylpent-4-en-1-yloxy)-thiazole-2(3H)-thione

There total 1 articles about (+/-)-5-(p-methoxyphenyl)-4-methyl-3-(2-phenylpent-4-en-1-yloxy)-thiazole-2(3H)-thione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 182194-86-1
2-phenyl-4-penten-1-yl p-toluenesulfonate

: N-(hydroxy)-5-(p-methoxyphenyl)-4-(methyl)thiazole-2(3H)-thione tetraethylammonium salt

: 902757-41-9
(+/-)-5-(p-methoxyphenyl)-4-methyl-3-(2-phenylpent-4-en-1-yloxy)-thiazole-2(3H)-thione

Guidance literature:: In N,N-dimethyl-formamide; at 20 ℃;
DOI:10.1039/b603480b

Reference yield: 87.0%

: 902757-41-9
(+/-)-5-(p-methoxyphenyl)-4-methyl-3-(2-phenylpent-4-en-1-yloxy)-thiazole-2(3H)-thione

: 688-73-3
tri-n-butyl-tin hydride

: 902757-51-1
5-(p-methoxyphenyl)-4-methyl-2-(tri-n-butylstannylsulfanyl)thiazole

Guidance literature:: In further solvent(s); byproducts: C6H5C4H6OCH3, CH2CHCH2CH(C6H5)CHO, CH2CCHCH2CH(C6H5)CH2OH; other Radiation; charging quartz glass vessel with thiazole deriv., 2.5 equiv. of tin compd. and C6H5CF3, microwave irradiating (2.45 GHz, 500 W) for 1 min at 80°C; evapn., chromy. (silica gel, petroleum ether-Et2O (2:1)), elem. anal.;
DOI:10.1039/b603480b

Reference yield: 77.0%

: 902757-41-9
(+/-)-5-(p-methoxyphenyl)-4-methyl-3-(2-phenylpent-4-en-1-yloxy)-thiazole-2(3H)-thione

: 688-73-3
tri-n-butyl-tin hydride

: 902757-51-1
5-(p-methoxyphenyl)-4-methyl-2-(tri-n-butylstannylsulfanyl)thiazole

: (+/-)-trans-2-methyl-4-phenyltetrahydrofuran

: (+/-)-cis-2-methyl-4-phenyltetrahydrofuran

Guidance literature:: With 2,2'-azobis(isobutyronitrile); In benzene-d6; at 80 ℃; diastereoselective reaction; Inert atmosphere;
DOI:10.1016/j.tet.2009.11.113