1,1a,6,6a-tetrahydro-1a-methyl-exo-1,6a-diphenyl-endo-6-ethenylcyclopropindene

Base Information

• Chemical Name: 1,1a,6,6a-tetrahydro-1a-methyl-exo-1,6a-diphenyl-endo-6-ethenylcycloprop
• Molecular Formula: C₂₅H₂₂
• Molecular Weight: 322.45

Synonyms:1,1a,6,6a-tetrahydro-1a-methyl-exo-1,6a-diphenyl-endo-6-ethenylcyclopropindene

Chemical Property of 1,1a,6,6a-tetrahydro-1a-methyl-exo-1,6a-diphenyl-endo-6-ethenylcycloprop

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There total 6 articles about 1,1a,6,6a-tetrahydro-1a-methyl-exo-1,6a-diphenyl-endo-6-ethenylcyclopropindene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(Z)-1-(propen-1-yl)-2-(1-methyl-2,3-diphenyl-2-cyclopropen-1-yl)benzene (70913-14-3) → 1,1a,6,6a-tetrahydro-1a-methyl-exo-1,6a-diphenyl-endo-6-ethenylcyclopropindene (70913-16-5)

Guidance literature:

In pyridine; benzene; at 160 ℃; for 0.5h;

DOI:10.1021/ja00292a042

Reference yield: 10.0%

3-methyl-1,2-diphenyl-3-(o-allylphenyl)cyclopropene (77333-71-2) → 1,1a,6,6a-tetrahydro-1a-methyl-exo-1,6a-diphenyl-endo-6-ethenylcyclopropindene (70913-16-5) + 5,5a,6,11,11a,12-hexahydro-5-methyl-5a-phenylcyclopropa-naphthacene (77333-74-5) + 4-Methyl-2,3-diphenyl-1-vinyl-1,2-dihydro-naphthalene (77333-73-4)

Guidance literature:

Irradiation;

DOI:10.1021/ja00397a056

Reference yield:

(Z)-1-(propen-1-yl)-2-(1-methyl-2,3-diphenyl-2-cyclopropen-1-yl)benzene (70913-14-3) → 1,1a,6,6a-tetrahydro-1a-methyl-exo-1,6a-diphenyl-endo-6-ethenylcyclopropindene (70913-16-5) + endo-(1α,1aβ,6α,6aβ)-1,1a,6,6a-tetrahydro-exo-1a,7-dimethyl-1,6a-diphenyl-1,6-methanocyclopropindene + exo-(1α,1aβ,6α,6aβ)-1,1a,6,6a-tetrahydro-exo-1a,7-dimethyl-1,6a-diphenyl-1,6-methanocyclopropindene

Guidance literature:

With thio-xanthene-9-one; In benzene; for 0.333333h; Product distribution; Irradiation; or heating;

DOI:10.1021/ja00292a042

upstream raw materials:

3-methyl-1,2-diphenyl-3-(o-allylphenyl)cyclopropene

(Z)-1-(propen-1-yl)-2-(1-methyl-2,3-diphenyl-2-cyclopropen-1-yl)benzene

(E)-1-(propen-1-yl)-2-(1-methyl-2,3-diphenyl-2-cyclopropen-1-yl)benzene

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