5-(3,5-di-tert-butylphenyl)-11-(4-diphenylaminostyryl)-1,1,3,3-tetraethylindeno[2,1-b]fluorene

Base Information

Chemical Name:5-(3,5-di-tert-butylphenyl)-11-(4-diphenylaminostyryl)-1,1,3,3-tetraethylindeno[2,1-b]fluorene
CAS No.:1377319-64-6
Molecular Formula:C₆₂H₆₅N
Molecular Weight:824.205
Hs Code.:

Synonyms:5-(3,5-di-tert-butylphenyl)-11-(4-diphenylaminostyryl)-1,1,3,3-tetraethylindeno[2,1-b]fluorene

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Chemical Property of 5-(3,5-di-tert-butylphenyl)-11-(4-diphenylaminostyryl)-1,1,3,3-tetraethylindeno[2,1-b]fluorene

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Technology Process of 5-(3,5-di-tert-butylphenyl)-11-(4-diphenylaminostyryl)-1,1,3,3-tetraethylindeno[2,1-b]fluorene

There total 5 articles about 5-(3,5-di-tert-butylphenyl)-11-(4-diphenylaminostyryl)-1,1,3,3-tetraethylindeno[2,1-b]fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1377319-65-7
11-(3,5-di-tert-butylphenyl)-1,1,3,3-tetraethyl-1,3-dihydroindeno[2,1-b]fluorene-5-carbaldehyde

: 126150-12-7
Diethyl (4-diphenylamino)benzyl phosphonate

: 1377319-64-6
5-(3,5-di-tert-butylphenyl)-11-(4-diphenylaminostyryl)-1,1,3,3-tetraethylindeno[2,1-b]fluorene

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at 0 - 20 ℃; for 1.25h; Inert atmosphere;
DOI:10.1002/ejoc.201200117

Reference yield:

: 525-18-8
10,12-dihydroindeno<2,1-b>fluorene

: 1377319-64-6
5-(3,5-di-tert-butylphenyl)-11-(4-diphenylaminostyryl)-1,1,3,3-tetraethylindeno[2,1-b]fluorene

Guidance literature:: Multi-step reaction with 5 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: iron(III) chloride; bromine / chloroform / 5 h / 0 - 20 °C / Darkness

3.1: n-butyllithium / tetrahydrofuran / -78 °C

3.2: -78 °C

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / ethanol; toluene / 120 °C

5.1: potassium tert-butylate / tetrahydrofuran / 1.25 h / 0 - 20 °C / Inert atmosphere

With iron(III) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; potassium tert-butylate; bromine; sodium carbonate; In tetrahydrofuran; ethanol; hexane; chloroform; toluene; 4.1: Suzuki coupling / 5.1: Horner-Wadsworth-Emmons olefination;
DOI:10.1002/ejoc.201200117

Reference yield:

: 1246963-92-7
5,11-dibromo-1,1,3,3-tetraethyl-1,3-dihydroindeno[2,1-b]fluorene

: 1377319-64-6
5-(3,5-di-tert-butylphenyl)-11-(4-diphenylaminostyryl)-1,1,3,3-tetraethylindeno[2,1-b]fluorene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran / -78 °C

1.2: -78 °C

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / ethanol; toluene / 120 °C

3.1: potassium tert-butylate / tetrahydrofuran / 1.25 h / 0 - 20 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; potassium tert-butylate; sodium carbonate; In tetrahydrofuran; ethanol; toluene; 2.1: Suzuki coupling / 3.1: Horner-Wadsworth-Emmons olefination;
DOI:10.1002/ejoc.201200117