N,N'-Diphenyl-1,4-epoxy-1,2,3,4,5,6,7,8-octahydronaphthalene-2-exo,3-exo-6,7-tetracarboximide

Base Information

• Chemical Name: N,N'-Diphenyl-1,4-epoxy-1,2,3,4,5,6,7,8-octahydronaphthalene-2-exo,3-exo-6,7-tetracarboximide
• CAS No.: 132869-41-1
• Molecular Formula: C₂₆H₂₀N₂O₅
• Molecular Weight: 440.455
• Mol file: 132869-41-1.mol

Synonyms:N,N'-Diphenyl-1,4-epoxy-1,2,3,4,5,6,7,8-octahydronaphthalene-2-exo,3-exo-6,7-tetracarboximide

Chemical Property of N,N'-Diphenyl-1,4-epoxy-1,2,3,4,5,6,7,8-octahydronaphthalene-2-exo,3-exo-6,7-tetracarboximide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-Diphenyl-1,4-epoxy-1,2,3,4,5,6,7,8-octahydronaphthalene-2-exo,3-exo-6,7-tetracarboximide

There total 4 articles about N,N'-Diphenyl-1,4-epoxy-1,2,3,4,5,6,7,8-octahydronaphthalene-2-exo,3-exo-6,7-tetracarboximide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

N-phenyl-maleimide (941-69-5) + 4H,6H-Dihydrothieno<3,4-c>furan 5,5-dioxide (119694-50-7) → N,N'-Diphenyl-1,4-epoxy-1,2,3,4,5,6,7,8-octahydronaphthalene-2-exo,3-exo-6,7-tetracarboximide (132869-41-1)

Guidance literature:

With 4-methoxy-phenol; In benzene; at 120 ℃; for 1h;

DOI:10.1039/a604600b

Reference yield:

3,4-dimethyl-3-sulfolene (18214-56-7) → N,N'-Diphenyl-1,4-epoxy-1,2,3,4,5,6,7,8-octahydronaphthalene-2-exo,3-exo-6,7-tetracarboximide (132869-41-1)

Guidance literature:

Multi-step reaction with 4 steps

1: 54 percent / N-bromosuccinimide (NBS) / CHCl₃ / 17 h / Heating

2: 93 percent / CF₃CO₂Ag / H₂O / 72 h / Ambient temperature

3: 72 percent / pyridinium chlorochromate (PCC), CF₃CO₂H / CH₂Cl₂ / 0.5 h / Ambient temperature

4: 72 percent / benzene / 1 h / 120 °C

With N-Bromosuccinimide; silver trifluoroacetate; pyridinium chlorochromate; trifluoroacetic acid; In dichloromethane; chloroform; water; benzene;

DOI:10.1039/c39900001687

Reference yield:

3,4-bis(hydroxymethyl)-2,5-dihydrothiophene 1,1-dioxide (50906-78-0) → N,N'-Diphenyl-1,4-epoxy-1,2,3,4,5,6,7,8-octahydronaphthalene-2-exo,3-exo-6,7-tetracarboximide (132869-41-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 72 percent / pyridinium chlorochromate (PCC), CF₃CO₂H / CH₂Cl₂ / 0.5 h / Ambient temperature

2: 72 percent / benzene / 1 h / 120 °C

With pyridinium chlorochromate; trifluoroacetic acid; In dichloromethane; benzene;

DOI:10.1039/c39900001687

upstream raw materials:

N-phenyl-maleimide

4H,6H-Dihydrothieno<3,4-c>furan 5,5-dioxide

3,4-dimethyl-3-sulfolene

3,4-bis(hydroxymethyl)-2,5-dihydrothiophene 1,1-dioxide