1-[(1S,6R)-6-vinyl-3-methylcyclohex-3-enyl]-2-hydroxy-1-ethanone

Base Information

• Chemical Name: 1-[(1S,6R)-6-vinyl-3-methylcyclohex-3-enyl]-2-hydroxy-1-ethanone
• CAS No.: 1240300-62-2
• Molecular Formula: C₁₁H₁₆O₂
• Molecular Weight: 180.247
• Mol file: 1240300-62-2.mol

Synonyms:1-[(1S,6R)-6-vinyl-3-methylcyclohex-3-enyl]-2-hydroxy-1-ethanone

Chemical Property of 1-[(1S,6R)-6-vinyl-3-methylcyclohex-3-enyl]-2-hydroxy-1-ethanone

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 1-[(1S,6R)-6-vinyl-3-methylcyclohex-3-enyl]-2-hydroxy-1-ethanone

There total 1 articles about 1-[(1S,6R)-6-vinyl-3-methylcyclohex-3-enyl]-2-hydroxy-1-ethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

(1S,6R,8R,10S)-10-iodomethyl-4-methyl-8-methoxy-9-oxabicyclo[4.4.0]dec-2-en-7-one (1240300-52-0) → 1-[(1S,6R)-6-vinyl-3-methylcyclohex-3-enyl]-2-hydroxy-1-ethanone (1240300-62-2)

Guidance literature:

With zinc; In water; isopropyl alcohol; for 5h; Reflux;

DOI:10.1134/S1070428010020144

Reference yield: 90.0%

1-[(1S,6R)-6-vinyl-3-methylcyclohex-3-enyl]-2-hydroxy-1-ethanone (1240300-62-2) → 1-[(1S,6R)-6-vinyl-3-methylcyclohex-3-enyl]-2-bromo-1-ethanone (1240300-63-3)

Guidance literature:

With carbon tetrabromide; triphenylphosphine; In dichloromethane; at 0 ℃; for 0.25h;

DOI:10.1134/S1070428010020144

upstream raw materials:

(1S,6R,8R,10S)-10-iodomethyl-4-methyl-8-methoxy-9-oxabicyclo[4.4.0]dec-2-en-7-one

Downstream raw materials:

1-[(1S,6R)-6-vinyl-3-methylcyclohex-3-enyl]-2-bromo-1-ethanone