4-(Benzyloxy)-2'-methyl-1,1'-biphenyl

Base Information

Chemical Name:4-(Benzyloxy)-2'-methyl-1,1'-biphenyl
CAS No.:893738-92-6
Molecular Formula:C₂₀H₁₈O
Molecular Weight:274.362
Hs Code.:
DSSTox Substance ID:DTXSID201272909

Synonyms:4-(Benzyloxy)-2'-methyl-1,1'-biphenyl;893738-92-6;DTXSID201272909;AKOS004118798;2-Methyl-4a(2)-(phenylmethoxy)-1,1a(2)-biphenyl

Suppliers and Price of 4-(Benzyloxy)-2'-methyl-1,1'-biphenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-(Benzyloxy)-2'-methyl-1,1'-biphenyl

Chemical Property:

XLogP3:5.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:274.135765193
Heavy Atom Count:21
Complexity:286

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=CC=C1C2=CC=C(C=C2)OCC3=CC=CC=C3

Technology Process of 4-(Benzyloxy)-2'-methyl-1,1'-biphenyl

There total 5 articles about 4-(Benzyloxy)-2'-methyl-1,1'-biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 7700-27-8
4-chlorophenyl benzyl ether

: C₁₉H₂₆BNO

: 893738-92-6
4-benzyloxy-2'?-methylbiphenyl

Guidance literature:: With triphenyl phosphite; potassium phosphate tribasic trihydrate; palladium diacetate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; In tert-butyl alcohol; at 80 ℃; for 12h; Inert atmosphere; Schlenk technique;
DOI:10.1016/j.jorganchem.2017.05.013

Reference yield: 91.0%

: 7700-27-8
4-chlorophenyl benzyl ether

: 73774-44-4
bis(2-methylphenyl)borinic acid

: 893738-92-6
4-benzyloxy-2'?-methylbiphenyl

Guidance literature:: With NiCl₂(Tris-(4-methoxy-phenyl)-phosphin)2; potassium phosphate tribasic trihydrate; P(p-CH₃OC₆H₄)3; In toluene; at 110 ℃; for 10h; Inert atmosphere;
DOI:10.1021/cs4009946

Reference yield:

: C₁₄H₁₆BO₂

: 893738-92-6
4-benzyloxy-2'?-methylbiphenyl

Guidance literature:: Multi-step reaction with 2 steps

1: ethyl acetate / 2 h / 20 °C / Inert atmosphere; Schlenk technique

2: potassium phosphate tribasic trihydrate; palladium diacetate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; triphenyl phosphite / tert-butyl alcohol / 12 h / 80 °C / Inert atmosphere; Schlenk technique

With triphenyl phosphite; potassium phosphate tribasic trihydrate; palladium diacetate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; In ethyl acetate; tert-butyl alcohol; 2: |Suzuki Coupling;
DOI:10.1016/j.jorganchem.2017.05.013