2P(C₆H₁₁)3*W*3CO*N₂ = (P(C₆H₁₁)3)2W(CO)3(N₂)

Base Information

• Chemical Name: 2P(C₆H₁₁)3*W*3CO*N₂ = (P(C₆H₁₁)3)2W(CO)3(N₂)
• CAS No.: 73690-57-0
• Molecular Formula: 3CO*2C₁₈H₃₃P*N₂*W
• Molecular Weight: 856.762
• Mol file: 73690-57-0.mol

Synonyms:2P(C₆H₁₁)3*W*3CO*N₂ = (P(C₆H₁₁)3)2W(CO)3(N₂)

Chemical Property of 2P(C₆H₁₁)3*W*3CO*N₂ = (P(C₆H₁₁)3)2W(CO)3(N₂)

Chemical Property:

Purity/Quality:

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Technology Process of 2P(C₆H₁₁)3*W*3CO*N₂ = (P(C₆H₁₁)3)2W(CO)3(N₂)

There total 5 articles about 2P(C₆H₁₁)3*W*3CO*N₂ = (P(C₆H₁₁)3)2W(CO)3(N₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

tricarbonyl(η6-cycloheptatriene)tungsten (12128-81-3) + nitrogen (7727-37-9) + tricyclohexylphosphine (2622-14-2) → trans-W(CO)3[P(C6H11)3]2N2 (73690-57-0)

Guidance literature:

In benzene; 30 min, N2-atmosphere;

DOI:10.1039/c39800000061

Reference yield:

2P(C6H11)3*W*3CO = (P(C6H11)3)2W(CO)3 (73690-56-9) → 2P(C6H11)3*W*3CO*N2 = (P(C6H11)3)2W(CO)3(N2) (73690-57-0)

Guidance literature:

With nitrogen; In toluene; soln. of W-complex in toluene, Schlenk tube, glove box, under Ar, addn. of N2, shaking for 30min; not isolated,;

DOI:10.1021/ja00192a021

Reference yield:

tricarbonyl(η6-cycloheptatriene)tungsten (12128-81-3) + tricyclohexylphosphine (2622-14-2) → 2P(C6H11)3*W*3CO*N2 = (P(C6H11)3)2W(CO)3(N2) (73690-57-0)

Guidance literature:

With N₂; In n-heptane; toluene; a mixt. of W(CO)3(C7H8), PCy3 in toluene was stirred under N2 for 30 min, heptane was added and stirring was continued for 45 min; ppt. was washed with 3:1 heptane-toluene, dried in a stream of N2;

DOI:10.1021/ja00269a027

upstream raw materials:

(P(C₆H₁₁)3)2W(CO)3

nitrogen

tricarbonyl(η6-cycloheptatriene)tungsten

tricyclohexylphosphine

Downstream raw materials:

W(CO)3(PCy₃)2(P(OMe)3)

(P(C₆H₁₁)3)2W(CO)3(H₂)

nitrogen

(η2-dihydrogen)W(CO)3(tricyclohexylphosphine)2