(N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine)(bis(1,4-diphenylphosphino)butane)rhodium(I) tetrafluoroborate

Base Information

• Chemical Name: (N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine)(bis(1,4-diphenylphosphino)butane)rhodium(I) tetrafluoroborate
• CAS No.: 380397-46-6
• Molecular Formula: BF₄*C₅₁H₅₂NOP₃Rh
• Molecular Weight: 977.611
• Mol file: 380397-46-6.mol

Synonyms:(N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine)(bis(1,4-diphenylphosphino)butane)rhodium(I) tetrafluoroborate

Chemical Property of (N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine)(bis(1,4-diphenylphosphino)butane)rhodium(I) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine)(bis(1,4-diphenylphosphino)butane)rhodium(I) tetrafluoroborate

There total 1 articles about (N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine)(bis(1,4-diphenylphosphino)butane)rhodium(I) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

[(bicyclo[2.2.1]hepta-2,5-diene)(1,4-bis(diphenylphosphino)butane)rhodium(I)] tetrafluoroborate + N-Methyl-N-propionyl-2-(diphenylphosphino) benzylamine (153358-14-6) → (N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine)(bis(1,4-diphenylphosphino)butane)rhodium(I) tetrafluoroborate (380397-46-6)

Guidance literature:

With H₂; In dichloromethane; under Ar, standard Schlenk techniques; CH2Cl2 added to equimolar mixt. of Rh complex and ligand; Ar atmosphere replaced with H2 (freeze-pump-thaw cycle); stirred for 40 min at room temp.; H2 replaced with Ar; stood for 5 min; solvent removed under vac.; washed with Et2O and n-hexane; dried under vac.; elem. anal.;

DOI:10.1021/om010543x

Reference yield: 99.0%

(N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine)(bis(1,4-diphenylphosphino)butane)rhodium(I) tetrafluoroborate (380397-46-6) → [Rh(I)H(DPPAM)(bis(1,4-diphenylphosphino)butane)][BF4] (380397-50-2)

Guidance literature:

In tetrahydrofuran; under N2, standard Schlenk techniques; stirred soln. of Rh complex in THF heated at 100°C for 90 min; solvent evapd. under vac.; elem. anal.;

DOI:10.1021/om010543x

upstream raw materials:

N-Methyl-N-propionyl-2-(diphenylphosphino) benzylamine

Downstream raw materials:

[Rh(I)H(DPPAM)(bis(1,4-diphenylphosphino)butane)][BF₄]