methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanoate

Base Information

Chemical Name:methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanoate
CAS No.:96056-22-3
Molecular Formula:C₂₀H₂₈O₅
Molecular Weight:348.439
Hs Code.:

Synonyms:methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanoate

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Chemical Property of methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanoate

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Technology Process of methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanoate

There total 1 articles about methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 96149-11-0
methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate

: 96056-22-3
methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanoate

Guidance literature:: With hydrogen; Rh on carbon; In pentane; for 5h; Ambient temperature;
DOI:10.1021/ja00297a037

Reference yield: 100.0%

: 96056-22-3
methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanoate

: 96056-23-4
3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propan-1-ol

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃; for 1h;
DOI:10.1021/ja00297a037

Reference yield:

: 96056-22-3
methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanoate

: 96056-11-0
3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanal

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / LAH / diethyl ether / 1 h / 0 °C

2: 97 percent / (COCl)2, Et₃N / CH₂Cl₂; dimethylsulfoxide / 0.25 h

With lithium aluminium tetrahydride; oxalyl dichloride; triethylamine; In diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/ja00297a037