N-{[(2S,5R,6S)-5-{2-[(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-4-methylphenylsulfonamido]methyl}allyloxy-6-methoxy-5,6-dihydro-2H-pyran-2-yl]methyl}-2-nitro-N-(prop-2'-ynyl)benzenesulfonamide

Base Information

Chemical Name:N-{[(2S,5R,6S)-5-{2-[(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-4-methylphenylsulfonamido]methyl}allyloxy-6-methoxy-5,6-dihydro-2H-pyran-2-yl]methyl}-2-nitro-N-(prop-2'-ynyl)benzenesulfonamide
CAS No.:1120367-66-9
Molecular Formula:C₃₇H₃₄F₁₇N₃O₉S₂
Molecular Weight:1051.8
Hs Code.:

N-{[(2S,5R,6S)-5-{2-[(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-4-methylphenylsulfonamido]methyl}allyloxy-6-methoxy-5,6-dihydro-2H-pyran-2-yl]methyl}-2-nitro-N-(prop-2'-ynyl)benzenesulfonamide

Synonyms:N-{[(2S,5R,6S)-5-{2-[(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-4-methylphenylsulfonamido]methyl}allyloxy-6-methoxy-5,6-dihydro-2H-pyran-2-yl]methyl}-2-nitro-N-(prop-2'-ynyl)benzenesulfonamide

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Chemical Property of N-{[(2S,5R,6S)-5-{2-[(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-4-methylphenylsulfonamido]methyl}allyloxy-6-methoxy-5,6-dihydro-2H-pyran-2-yl]methyl}-2-nitro-N-(prop-2'-ynyl)benzenesulfonamide

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Technology Process of N-{[(2S,5R,6S)-5-{2-[(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-4-methylphenylsulfonamido]methyl}allyloxy-6-methoxy-5,6-dihydro-2H-pyran-2-yl]methyl}-2-nitro-N-(prop-2'-ynyl)benzenesulfonamide

There total 1 articles about N-{[(2S,5R,6S)-5-{2-[(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-4-methylphenylsulfonamido]methyl}allyloxy-6-methoxy-5,6-dihydro-2H-pyran-2-yl]methyl}-2-nitro-N-(prop-2'-ynyl)benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1120367-44-3
N-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-N-[2-{[(2S,3R,6S)-2-methoxy-6-{(2-nitrophenylsulfonamido)methyl}-3,6-dihydro-2H-pyran-3-yloxy]methyl}allyl]-4-methylbenzenesulfonamide

: 107-19-7
propargyl alcohol

: 1120367-66-9
N-{[(2S,5R,6S)-5-{2-[(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-4-methylphenylsulfonamido]methyl}allyloxy-6-methoxy-5,6-dihydro-2H-pyran-2-yl]methyl}-2-nitro-N-(prop-2'-ynyl)benzenesulfonamide

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/ol802848j

Reference yield: 53.0%

: 1120367-66-9
N-{[(2S,5R,6S)-5-{2-[(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-4-methylphenylsulfonamido]methyl}allyloxy-6-methoxy-5,6-dihydro-2H-pyran-2-yl]methyl}-2-nitro-N-(prop-2'-ynyl)benzenesulfonamide

: 1120367-52-3
N-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-N-[{(R)-5-[(S)-methoxy{(S)-1'-(nitrophenylsulfonyl)-5'-vinyl-1',2',3',6'-tetrahydropyridin-3'-yloxy}methyl]-2,5-dihydrofuran-3-yl}methyl]-4-methylbenzenesulfonamide

Guidance literature:: N-{[(2S,5R,6S)-5-{2-[(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-4-methylphenylsulfonamido]methyl}allyloxy-6-methoxy-5,6-dihydro-2H-pyran-2-yl]methyl}-2-nitro-N-(prop-2'-ynyl)benzenesulfonamide; With Hoveyda-Grubbs catalyst second generation; In dichloromethane; for 168h; Inert atmosphere; Reflux;

With tris(hydroxymethyl)phosphine; triethylamine; In dichloromethane; at 20 ℃; Inert atmosphere;

With silica gel; In dichloromethane; for 1h; Inert atmosphere;
DOI:10.1021/ol802848j