2-(tert-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1H-imidazol-4-yl)-3-oxo-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester

Base Information

Chemical Name:2-(tert-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1H-imidazol-4-yl)-3-oxo-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester
CAS No.:908597-34-2
Molecular Formula:C₄₀H₅₅N₃O₇Si
Molecular Weight:717.978
Hs Code.:

2-(<i>tert</i>-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1<i>H</i>-imidazol-4-yl)-3-oxo-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester

Synonyms:2-(tert-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1H-imidazol-4-yl)-3-oxo-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester

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Chemical Property of 2-(tert-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1H-imidazol-4-yl)-3-oxo-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester

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Technology Process of 2-(tert-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1H-imidazol-4-yl)-3-oxo-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester

There total 8 articles about 2-(tert-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1H-imidazol-4-yl)-3-oxo-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2-(tert-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1H-imidazol-4-yl)-3-hydroxy-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester

: 908597-34-2
2-(tert-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1H-imidazol-4-yl)-3-oxo-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester

Guidance literature:: With Dess-Martin periodane; In dichloromethane; water;
DOI:10.1002/anie.200601208

Reference yield:

: 908597-61-5
3-tert-butoxycarbonylamino-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester

: 908597-34-2
2-(tert-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1H-imidazol-4-yl)-3-oxo-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium hexamethyldisilazide / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: boron trifluoride diethyl etherate / tetrahydrofuran; hexane / 0.75 h / -78 °C

2.1: 90 mg / Dess-Martin periodinane / CH₂Cl₂; H₂O

With Dess-Martin periodane; lithium hexamethyldisilazane; In tetrahydrofuran; hexane; dichloromethane; water;
DOI:10.1002/anie.200601208

Reference yield:

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 908597-34-2
2-(tert-butoxycarbonylamino-methyl)-3-(1,3-dibenzyl-2-oxo-2,3-dihydro-1H-imidazol-4-yl)-3-oxo-propionic acid 4-triisopropylsilanyloxy-cyclopent-2-enyl ester

Guidance literature:: Multi-step reaction with 5 steps

1.1: 2,6-lutidine / CH₂Cl₂ / 18 h / 23 °C

2.1: lithium hydroxide / tetrahydrofuran; H₂O / 18 h / 23 °C

3.1: 175 mg / triphenylphosphine; diethyl azodicarboxylate / tetrahydrofuran / 5 h / 23 °C

4.1: lithium hexamethyldisilazide / tetrahydrofuran; hexane / 0.5 h / -78 °C

4.2: boron trifluoride diethyl etherate / tetrahydrofuran; hexane / 0.75 h / -78 °C

5.1: 90 mg / Dess-Martin periodinane / CH₂Cl₂; H₂O

With 2,6-dimethylpyridine; lithium hydroxide; Dess-Martin periodane; triphenylphosphine; lithium hexamethyldisilazane; diethylazodicarboxylate; In tetrahydrofuran; hexane; dichloromethane; water;
DOI:10.1002/anie.200601208