C₆₀H₇₈O₇

Base Information

• Chemical Name: C₆₀H₇₈O₇
• CAS No.: 1558035-02-1
• Molecular Formula: C₆₀H₇₈O₇
• Molecular Weight: 911.275
• Mol file: 1558035-02-1.mol

Synonyms:C₆₀H₇₈O₇

Chemical Property of C₆₀H₇₈O₇

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₀H₇₈O₇

There total 15 articles about C₆₀H₇₈O₇ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

C68H86O8 (1558035-04-3) → C60H78O7 (1558035-02-1)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; at 0 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/ol5002686

Reference yield:

1-(3',4',6'-tri-O-benzyl-α-D-galactopyranosyl)-2-propene (271246-08-3) → C60H78O7 (1558035-02-1)

Guidance literature:

Multi-step reaction with 6 steps

1.1: pyridine; dmap / 16 h / 20 °C / Inert atmosphere

2.1: 2,4,6-trichlorobenzoyl chloride; triethylamine / tetrahydrofuran / 4 h / 0 °C / Inert atmosphere

2.2: 1 h / 20 °C / Inert atmosphere

3.1: ethene; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 2 h / 40 °C

4.1: diisobutylaluminium hydride / dichloromethane; hexane / 3 h / -78 - 20 °C / Inert atmosphere

5.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 3 h / 0 - 20 °C / Inert atmosphere

6.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 0.5 h / 0 °C / Inert atmosphere

With pyridine; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; dmap; ethene; 2,4,6-trichlorobenzoyl chloride; sodium hydride; diisobutylaluminium hydride; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; hexane; dichloromethane; water; N,N-dimethyl-formamide; mineral oil;

DOI:10.1021/ol5002686

Reference yield:

C38H38O8 (1558034-99-3) → C60H78O7 (1558035-02-1)

Guidance literature:

Multi-step reaction with 5 steps

1.1: 2,4,6-trichlorobenzoyl chloride; triethylamine / tetrahydrofuran / 4 h / 0 °C / Inert atmosphere

1.2: 1 h / 20 °C / Inert atmosphere

2.1: ethene; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 2 h / 40 °C

3.1: diisobutylaluminium hydride / dichloromethane; hexane / 3 h / -78 - 20 °C / Inert atmosphere

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 3 h / 0 - 20 °C / Inert atmosphere

5.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 0.5 h / 0 °C / Inert atmosphere

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; ethene; 2,4,6-trichlorobenzoyl chloride; sodium hydride; diisobutylaluminium hydride; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; hexane; dichloromethane; water; N,N-dimethyl-formamide; mineral oil;

DOI:10.1021/ol5002686

upstream raw materials:

1-(3',4',6'-tri-O-benzyl-α-D-galactopyranosyl)-2-propene

C₃₈H₃₈O₈

C₆₄H₈₀O₁₀

C₆₂H₇₆O₁₀

Downstream raw materials:

C₆₈H₈₄INO₈

C₆₈H₈₅NO₈

C₆₇H₈₇NO₇

C₆₉H₈₇NO₇S