(E)-N-methyl-N-(3-phenyl-2-propenyl)-1,2,3,4-tetrahydro-1,4-methano-5-naphthalenemethanamine

Base Information

Chemical Name:(E)-N-methyl-N-(3-phenyl-2-propenyl)-1,2,3,4-tetrahydro-1,4-methano-5-naphthalenemethanamine
CAS No.:98977-68-5
Molecular Formula:C₂₂H₂₅N
Molecular Weight:303.447
Hs Code.:

Synonyms:(E)-N-methyl-N-(3-phenyl-2-propenyl)-1,2,3,4-tetrahydro-1,4-methano-5-naphthalenemethanamine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-N-methyl-N-(3-phenyl-2-propenyl)-1,2,3,4-tetrahydro-1,4-methano-5-naphthalenemethanamine

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Technology Process of (E)-N-methyl-N-(3-phenyl-2-propenyl)-1,2,3,4-tetrahydro-1,4-methano-5-naphthalenemethanamine

There total 7 articles about (E)-N-methyl-N-(3-phenyl-2-propenyl)-1,2,3,4-tetrahydro-1,4-methano-5-naphthalenemethanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 60960-88-5,93085-46-2,83554-67-0
(E)-N-methylcinnamylamine

: 98978-45-1
5-(chloromethyl)-1,2,3,4-tetrahydro-1,4-methanonaphthalene

: 98977-68-5
(E)-N-methyl-N-(3-phenyl-2-propenyl)-1,2,3,4-tetrahydro-1,4-methano-5-naphthalenemethanamine

Guidance literature:: With sodium carbonate; In N,N-dimethyl-formamide; Ambient temperature;
DOI:10.1021/jm00151a019

Reference yield:

: 498-66-8
norborn-2-ene

: 98977-68-5
(E)-N-methyl-N-(3-phenyl-2-propenyl)-1,2,3,4-tetrahydro-1,4-methano-5-naphthalenemethanamine

Guidance literature:: Multi-step reaction with 6 steps

1: 36 percent / dioxane / 200 °C

2: N-bromosuccinimide (NBS), α,α'-azobis(isobutyronitrile) / CCl4 / 1 h / Heating

3: 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) / benzene / Ambient temperature

4: 81 percent / diisobutylaluminium chloride (dibal) / toluene / -10 °C

5: 100 percent / SOCl₂

6: 48 percent / Na₂CO₃ / dimethylformamide / Ambient temperature

With N-Bromosuccinimide; thionyl chloride; azobisisobutyronitrile; diisobutylaluminum chloride; sodium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In 1,4-dioxane; tetrachloromethane; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1021/jm00151a019

Reference yield:

: (1,2,3,4-Tetrahydro-1,4-methano-naphthalen-5-yl)-methanol

: 98977-68-5
(E)-N-methyl-N-(3-phenyl-2-propenyl)-1,2,3,4-tetrahydro-1,4-methano-5-naphthalenemethanamine

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / SOCl₂

2: 48 percent / Na₂CO₃ / dimethylformamide / Ambient temperature

With thionyl chloride; sodium carbonate; In N,N-dimethyl-formamide;
DOI:10.1021/jm00151a019