1,3-bis(2,6-dimethylphenyl)-2-iodo-2,3-dihydro-1H-1,3,2-diazaborol0e

Base Information

• Chemical Name: 1,3-bis(2,6-dimethylphenyl)-2-iodo-2,3-dihydro-1H-1,3,2-diazaborol0e
• CAS No.: 212375-84-3
• Molecular Formula: C₁₈H₂₀BIN₂
• Molecular Weight: 402.086
• Mol file: 212375-84-3.mol

Synonyms:1,3-bis(2,6-dimethylphenyl)-2-iodo-2,3-dihydro-1H-1,3,2-diazaborol0e

Chemical Property of 1,3-bis(2,6-dimethylphenyl)-2-iodo-2,3-dihydro-1H-1,3,2-diazaborol0e

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-bis(2,6-dimethylphenyl)-2-iodo-2,3-dihydro-1H-1,3,2-diazaborol0e

There total 1 articles about 1,3-bis(2,6-dimethylphenyl)-2-iodo-2,3-dihydro-1H-1,3,2-diazaborol0e which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

glyoxalbis(2,6-dimethylphenylimine) + boron triiodide (13517-10-7) → 1,3-bis(2,6-dimethylphenyl)-2-iodo-2,3-dihydro-1H-1,3,2-diazaborol0e (212375-84-3)

Guidance literature:

In hexane; dichloromethane; Ar atmosphere, addn. of CH2Cl2 soln. of 1,4-diazabutadiene and n-hexane soln. of BCl3 into a mixture of n-hexane and CH2Cl2 at -10°C, filtration, warming to room temp., stirring ( 5 d); filtration, concn. to dryness, extn. (n-hexane), decantation, concn. of combined filtrates, crystn. (-4°C, 3 d), sublimation (380°C, 0.01 Torr); elem. anal.;

DOI:10.1002/(SICI)1099-0682(199808)1998:8<1145::AID-EJIC1145>3.0.CO;2-H

Reference yield: 93.0%

silver thiocyanate (1701-93-5) + 1,3-bis(2,6-dimethylphenyl)-2-iodo-2,3-dihydro-1H-1,3,2-diazaborol0e (212375-84-3) → C19H20BN3S (212375-89-8)

Guidance literature:

In acetonitrile; byproducts: AgI; Ar atmosphere, addn. of AgSCN to a slurry of diazaborole in CH3CN, stirring (20°C, 5 h); filtration, concn. to dryness, extn. (n-hexane), filtration, removement of volatiles; elem. anal.;

DOI:10.1002/(SICI)1099-0682(199808)1998:8<1145::AID-EJIC1145>3.0.CO;2-H

Reference yield: 89.0%

1,3-bis(2,6-dimethylphenyl)-2-iodo-2,3-dihydro-1H-1,3,2-diazaborol0e (212375-84-3) → 1,3-bis(2,6-dimethylphenyl)-2,3-dihydro-1H-1,3,2-diazaborole

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 0.0833333h; Ambient temperature;

DOI:10.1002/(SICI)1099-0682(199903)1999:3<491::AID-EJIC491>3.0.CO;2-9

upstream raw materials:

boron triiodide

Downstream raw materials:

C₁₉H₂₀BN₃

C₁₉H₂₀BN₃S