C₆₃H₁₀₄O₈SSi₅

Base Information

Chemical Name:C₆₃H₁₀₄O₈SSi₅
CAS No.:945468-76-8
Molecular Formula:C₆₃H₁₀₄O₈SSi₅
Molecular Weight:1162.01
Hs Code.:

C<sub>63</sub>H<sub>104</sub>O<sub>8</sub>SSi<sub>5</sub>

Synonyms:C₆₃H₁₀₄O₈SSi₅

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Chemical Property of C₆₃H₁₀₄O₈SSi₅

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Technology Process of C₆₃H₁₀₄O₈SSi₅

There total 35 articles about C₆₃H₁₀₄O₈SSi₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 945468-75-7
C₅₇H₈₈O₈SSi₃

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 945468-76-8
C₆₃H₁₀₄O₈SSi₅

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -30 ℃; for 3h;
DOI:10.1016/j.tetlet.2007.04.136

Reference yield:

: C₁₇H₂₄O₅

: 945468-76-8
C₆₃H₁₀₄O₈SSi₅

Guidance literature:: Multi-step reaction with 17 steps

1.1: 73 percent / DIBALH / CH₂Cl₂ / 0.67 h / -78 °C

2.1: (+)-diisopropyl tartrate; Ti(OiPr)4; TBHP / 4A MS / CH₂Cl₂ / 12 h / -30 °C

3.1: 100 percent / LiAlH₄ / tetrahydrofuran / 1 h / 24 °C

4.1: 95 percent / 2,6-lutidine / CH₂Cl₂ / 0.75 h / -40 °C

5.1: 89 percent / K₂CO₃ / methanol / 0.03 h / 23 °C

6.1: 87 percent / TPAP; NMO; 4A MS / CH₂Cl₂ / 0.5 h / 0 °C

7.1: NaH / benzene; tetrahydrofuran / 0.08 h / 0 °C

7.2: 85 percent / benzene; tetrahydrofuran / 8 h / -78 °C

8.1: 98 percent / NaBH₄; CeCl₃*H₂O / ethanol / 3 h / -20 °C

9.1: 93 percent / K₂CO₃ / methanol / 2 h / 24 °C

10.1: 95 percent / m-CPBA; NaHCO₃ / CH₂Cl₂ / 2 h / 0 °C

11.1: 2,6-lutidine / CH₂Cl₂ / 1 h / -20 °C

12.1: 77 percent / CSA / CH₂Cl₂ / 4 h / 0 °C

13.1: 95 percent / pyridine / CH₂Cl₂ / 2 h / 0 °C

14.1: 95 percent / TMSOTf; 2,6-lutidine / CH₂Cl₂ / 2 h / 0 °C

15.1: 94 percent / Bu₃P / CH₂Cl₂ / 1 h / 25 °C

16.1: 100 percent / LiAlH₄ / diethyl ether / 1.5 h / -30 °C

17.1: 93 percent / 2,6-lutidine / CH₂Cl₂ / 3 h / -30 °C

With pyridine; 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium tetrahydroborate; lithium aluminium tetrahydride; N-methyl-2-indolinone; cerium(III) chloride; tetrapropylammonium perruthennate; L-(+)-diisopropyl tartrate; tributylphosphine; trimethylsilyl trifluoromethanesulfonate; camphor-10-sulfonic acid; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; 4A MS; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; benzene; 2.1: Katsuki-Sharpless asymmetric epoxidation / 7.1: Horner-Wadsworth-Emmons reaction;
DOI:10.1016/j.tetlet.2007.04.136

Reference yield:

: 945468-63-3
C₁₅H₂₂O₄

: 945468-76-8
C₆₃H₁₀₄O₈SSi₅

Guidance literature:: Multi-step reaction with 16 steps

1.1: (+)-diisopropyl tartrate; Ti(OiPr)4; TBHP / 4A MS / CH₂Cl₂ / 12 h / -30 °C

2.1: 100 percent / LiAlH₄ / tetrahydrofuran / 1 h / 24 °C

3.1: 95 percent / 2,6-lutidine / CH₂Cl₂ / 0.75 h / -40 °C

4.1: 89 percent / K₂CO₃ / methanol / 0.03 h / 23 °C

5.1: 87 percent / TPAP; NMO; 4A MS / CH₂Cl₂ / 0.5 h / 0 °C

6.1: NaH / benzene; tetrahydrofuran / 0.08 h / 0 °C

6.2: 85 percent / benzene; tetrahydrofuran / 8 h / -78 °C

7.1: 98 percent / NaBH₄; CeCl₃*H₂O / ethanol / 3 h / -20 °C

8.1: 93 percent / K₂CO₃ / methanol / 2 h / 24 °C

9.1: 95 percent / m-CPBA; NaHCO₃ / CH₂Cl₂ / 2 h / 0 °C

10.1: 2,6-lutidine / CH₂Cl₂ / 1 h / -20 °C

11.1: 77 percent / CSA / CH₂Cl₂ / 4 h / 0 °C

12.1: 95 percent / pyridine / CH₂Cl₂ / 2 h / 0 °C

13.1: 95 percent / TMSOTf; 2,6-lutidine / CH₂Cl₂ / 2 h / 0 °C

14.1: 94 percent / Bu₃P / CH₂Cl₂ / 1 h / 25 °C

15.1: 100 percent / LiAlH₄ / diethyl ether / 1.5 h / -30 °C

16.1: 93 percent / 2,6-lutidine / CH₂Cl₂ / 3 h / -30 °C

With pyridine; 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium tetrahydroborate; lithium aluminium tetrahydride; N-methyl-2-indolinone; cerium(III) chloride; tetrapropylammonium perruthennate; L-(+)-diisopropyl tartrate; tributylphosphine; trimethylsilyl trifluoromethanesulfonate; camphor-10-sulfonic acid; sodium hydride; sodium hydrogencarbonate; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; 4A MS; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; benzene; 1.1: Katsuki-Sharpless asymmetric epoxidation / 6.1: Horner-Wadsworth-Emmons reaction;
DOI:10.1016/j.tetlet.2007.04.136