N'-[5-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-1,4-dimethyl-hexylidene]-N,N-dimethyl-hydrazine

Base Information

Chemical Name:N'-[5-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-1,4-dimethyl-hexylidene]-N,N-dimethyl-hydrazine
CAS No.:743472-07-3
Molecular Formula:C₂₄H₄₄N₂O₃Si
Molecular Weight:436.71
Hs Code.:

<i>N</i>'-[5-(<i>tert</i>-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-1,4-dimethyl-hexylidene]-<i>N</i>,<i>N</i>-dimethyl-hydrazine

Synonyms:N'-[5-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-1,4-dimethyl-hexylidene]-N,N-dimethyl-hydrazine

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Chemical Property of N'-[5-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-1,4-dimethyl-hexylidene]-N,N-dimethyl-hydrazine

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Technology Process of N'-[5-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-1,4-dimethyl-hexylidene]-N,N-dimethyl-hydrazine

There total 8 articles about N'-[5-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-1,4-dimethyl-hexylidene]-N,N-dimethyl-hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 743472-07-3
N'-[5-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-1,4-dimethyl-hexylidene]-N,N-dimethyl-hydrazine

Guidance literature:: Multi-step reaction with 5 steps

1: 2,6-lutidine / CH₂Cl₂ / 0.25 h / 25 °C

2: DIBALH / CH₂Cl₂ / 0.5 h / 0 °C

3: LiCl; DIPEA / acetonitrile / 25 °C

4: H₂ / Pd/C / methanol

5: TMSCl / 18 h / 25 °C

With 2,6-dimethylpyridine; chloro-trimethyl-silane; hydrogen; diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; lithium chloride; palladium on activated charcoal; In methanol; dichloromethane; acetonitrile; 3: Horner-Wadsworth-Emmons reaction;
DOI:10.1021/ol0491078

Reference yield:

: 121289-23-4
p-methoxybenzyloxyacetaldehyde

: 743472-07-3
N'-[5-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-1,4-dimethyl-hexylidene]-N,N-dimethyl-hydrazine

Guidance literature:: Multi-step reaction with 7 steps

1.1: n-Bu₂BOTf; Et₃N / CH₂Cl₂ / -5 °C

1.2: CH₂Cl₂ / 3 h / -78 °C

2.1: Me₃Al / tetrahydrofuran / 2 h / 0 °C

3.1: 2,6-lutidine / CH₂Cl₂ / 0.25 h / 25 °C

4.1: DIBALH / CH₂Cl₂ / 0.5 h / 0 °C

5.1: LiCl; DIPEA / acetonitrile / 25 °C

6.1: H₂ / Pd/C / methanol

7.1: TMSCl / 18 h / 25 °C

With 2,6-dimethylpyridine; chloro-trimethyl-silane; di-n-butylboryl trifluoromethanesulfonate; hydrogen; trimethylaluminum; diisobutylaluminium hydride; triethylamine; N-ethyl-N,N-diisopropylamine; lithium chloride; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; acetonitrile; 5.1: Horner-Wadsworth-Emmons reaction;
DOI:10.1021/ol0491078

Reference yield:

: 3-hydroxy-N-methoxy-4-(4-methoxy-benzyloxy)-2,N-dimethyl-butyramide

: 743472-07-3
N'-[5-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-1,4-dimethyl-hexylidene]-N,N-dimethyl-hydrazine

Guidance literature:: Multi-step reaction with 5 steps

1: 2,6-lutidine / CH₂Cl₂ / 0.25 h / 25 °C

2: DIBALH / CH₂Cl₂ / 0.5 h / 0 °C

3: LiCl; DIPEA / acetonitrile / 25 °C

4: H₂ / Pd/C / methanol

5: TMSCl / 18 h / 25 °C

With 2,6-dimethylpyridine; chloro-trimethyl-silane; hydrogen; diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; lithium chloride; palladium on activated charcoal; In methanol; dichloromethane; acetonitrile; 3: Horner-Wadsworth-Emmons reaction;
DOI:10.1021/ol0491078