1-(4'-methoxy-3'-methoxymethoxyphenyl)-1-(3'',4'',5''-trimethoxyphenyl)ethylene

Base Information

Chemical Name:1-(4'-methoxy-3'-methoxymethoxyphenyl)-1-(3'',4'',5''-trimethoxyphenyl)ethylene
CAS No.:1416990-96-9
Molecular Formula:C₂₀H₂₄O₆
Molecular Weight:360.407
Hs Code.:

Synonyms:1-(4'-methoxy-3'-methoxymethoxyphenyl)-1-(3'',4'',5''-trimethoxyphenyl)ethylene

Suppliers and Price of 1-(4'-methoxy-3'-methoxymethoxyphenyl)-1-(3'',4'',5''-trimethoxyphenyl)ethylene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-(4'-methoxy-3'-methoxymethoxyphenyl)-1-(3'',4'',5''-trimethoxyphenyl)ethylene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-(4'-methoxy-3'-methoxymethoxyphenyl)-1-(3'',4'',5''-trimethoxyphenyl)ethylene

There total 9 articles about 1-(4'-methoxy-3'-methoxymethoxyphenyl)-1-(3'',4'',5''-trimethoxyphenyl)ethylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1170045-84-7
4-methyl-N′-(1-(3,4,5-trimethoxyphenyl)ethylidene)benzenesulfonohydrazide

: 1416990-96-9
1-(4'-methoxy-3'-methoxymethoxyphenyl)-1-(3'',4'',5''-trimethoxyphenyl)ethylene

Guidance literature:: 4-methyl-N′-(1-(3,4,5-trimethoxyphenyl)ethylidene)benzenesulfonohydrazide; With dichloro bis(acetonitrile) palladium(II); 1,3-bis-(diphenylphosphino)propane; In 1,4-dioxane; at 20 ℃; for 0.0833333h; Inert atmosphere;

4-halo-1-methoxy-2-(methoxymethoxy)benzene; With caesium carbonate; In 1,4-dioxane; at 90 ℃; Inert atmosphere;
DOI:10.1039/c2ob26253c

Reference yield: 81.0%

: 4-iodo-1-methoxy-2-(methoxymethoxy)benzene

: 1-iodo-1-(3,4,5-trimethoxyphenyl)ethylene

: 1416990-96-9
1-(4'-methoxy-3'-methoxymethoxyphenyl)-1-(3'',4'',5''-trimethoxyphenyl)ethylene

Guidance literature:: 1-iodo-1-(3,4,5-trimethoxyphenyl)ethylene; With TurboGrignard; In tetrahydrofuran; at -20 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

With zinc(II) chloride; In tetrahydrofuran; at -20 - 20 ℃;

4-iodo-1-methoxy-2-(methoxymethoxy)benzene; With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; In tetrahydrofuran; at 20 ℃; for 5h; Inert atmosphere;
DOI:10.1055/s-0033-1339334

Reference yield:

: 90-05-1
2-methoxy-phenol

: 1416990-96-9
1-(4'-methoxy-3'-methoxymethoxyphenyl)-1-(3'',4'',5''-trimethoxyphenyl)ethylene

Guidance literature:: Multi-step reaction with 5 steps

1.1: pyridine / dichloromethane / 0.5 h

2.1: Iodine monochloride / dichloromethane / 2 h / Cooling

3.1: lithium hydroxide monohydrate; hydrogenchloride / tetrahydrofuran; methanol; water / 3.5 h / 20 °C

4.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 10 h / 0 - 20 °C

5.1: TurboGrignard / tetrahydrofuran / 0.33 h / -20 °C / Inert atmosphere; Schlenk technique

5.2: -20 - 20 °C

5.3: 5 h / 20 °C / Inert atmosphere

With pyridine; hydrogenchloride; TurboGrignard; lithium hydroxide monohydrate; Iodine monochloride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; dichloromethane; water; 5.2: |Negishi Coupling / 5.3: |Negishi Coupling;
DOI:10.1055/s-0033-1339334