NiCl(C₆H₅B(CH₂P(CH(CH₃)2)2)3)

Base Information

Chemical Name:NiCl(C₆H₅B(CH₂P(CH(CH₃)2)2)3)
CAS No.:741735-77-3
Molecular Formula:C₂₇H₅₃BClNiP₃
Molecular Weight:575.593
Hs Code.:

NiCl(C<sub>6</sub>H<sub>5</sub>B(CH<sub>2</sub>P(CH(CH<sub>3</sub>)2)2)3)

Synonyms:NiCl(C₆H₅B(CH₂P(CH(CH₃)2)2)3)

Suppliers and Price of NiCl(C₆H₅B(CH₂P(CH(CH₃)2)2)3)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of NiCl(C₆H₅B(CH₂P(CH(CH₃)2)2)3)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of NiCl(C₆H₅B(CH₂P(CH(CH₃)2)2)3)

There total 1 articles about NiCl(C₆H₅B(CH₂P(CH(CH₃)2)2)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.8%

: 29046-78-4
(1,2-dimethoxyethane)dichloronickel(II)

: 579444-61-4
Tl[PhB(CH₂P(i)Pr₂)3]

: 741735-77-3
NiCl(C₆H₅B(CH₂P(CH(CH₃)2)2)3)

Guidance literature:: In tetrahydrofuran; byproducts: TlCl; under N2; Ni-complex was suspended in THF, THF soln. of Tl-complex was added dropwise over 10 min with stirring, stirred for 25 min; filtered, washed with benzene, concd. under reduced pressure, dissolved in benzene, filtered, lyophilized; elem. anal.;
DOI:10.1021/ic049936p

Reference yield: 98.4%

: 741735-77-3
NiCl(C₆H₅B(CH₂P(CH(CH₃)2)2)3)

: 594-09-2
trimethylphosphane

: 741735-88-6
Ni(C₆H₅B(CH₂P(CH(CH₃)2)2)3)P(CH₃)3

Guidance literature:: With Na/Hg; In tetrahydrofuran; under N2; PMe3 was added to soln. of Ni-complex in THF, 10 min, transferred to vial with Na/Hg, stirred for 4 h; filtered, washed with benzene, concd. to dryness under reduced pressure;elem. anal.;
DOI:10.1021/ic049936p

Reference yield: 92.0%

: 579444-77-2
(isopropyl)2PCH₂Li

: 741735-77-3
NiCl(C₆H₅B(CH₂P(CH(CH₃)2)2)3)

: 741735-84-2
[PhB(CH2PiPr2)3]Ni(η2-CH2PiPr2)

Guidance literature:: In tetrahydrofuran; under N2; THF soln. of Li-salt was added dropwise to stirred THF soln. of Ni-complex, 30 min; volatiles were removed under reduced pressure, extd. with benzene, filtered, volatiles were removed under reduced pressure;
DOI:10.1021/ic049936p