3,3'-(4,4'-(4,4'-(4,4'-(phenylazanediyl)bis(4,1-phenylene))-bis(1H-1,2,3-triazole-4,1-diyl))bis(2,5-bis(hexyloxy)-4,1-phenylene))bis(2-cyanoacrylic acid)

Base Information

Chemical Name:3,3'-(4,4'-(4,4'-(4,4'-(phenylazanediyl)bis(4,1-phenylene))-bis(1H-1,2,3-triazole-4,1-diyl))bis(2,5-bis(hexyloxy)-4,1-phenylene))bis(2-cyanoacrylic acid)
CAS No.:1360630-00-7
Molecular Formula:C₆₆H₇₅N₉O₈
Molecular Weight:1122.38
Hs Code.:

Synonyms:3,3'-(4,4'-(4,4'-(4,4'-(phenylazanediyl)bis(4,1-phenylene))-bis(1H-1,2,3-triazole-4,1-diyl))bis(2,5-bis(hexyloxy)-4,1-phenylene))bis(2-cyanoacrylic acid)

Suppliers and Price of 3,3'-(4,4'-(4,4'-(4,4'-(phenylazanediyl)bis(4,1-phenylene))-bis(1H-1,2,3-triazole-4,1-diyl))bis(2,5-bis(hexyloxy)-4,1-phenylene))bis(2-cyanoacrylic acid)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,3'-(4,4'-(4,4'-(4,4'-(phenylazanediyl)bis(4,1-phenylene))-bis(1H-1,2,3-triazole-4,1-diyl))bis(2,5-bis(hexyloxy)-4,1-phenylene))bis(2-cyanoacrylic acid)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,3'-(4,4'-(4,4'-(4,4'-(phenylazanediyl)bis(4,1-phenylene))-bis(1H-1,2,3-triazole-4,1-diyl))bis(2,5-bis(hexyloxy)-4,1-phenylene))bis(2-cyanoacrylic acid)

There total 4 articles about 3,3'-(4,4'-(4,4'-(4,4'-(phenylazanediyl)bis(4,1-phenylene))-bis(1H-1,2,3-triazole-4,1-diyl))bis(2,5-bis(hexyloxy)-4,1-phenylene))bis(2-cyanoacrylic acid) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 4-ethynyl-N-(4-ethynylphenyl)-N-phenylbenzenamine

: 1360629-98-6
3-(4-azido-2,5-bis(hexyloxy)phenyl)-2-cyanoacrylic acid

: 1360630-00-7
3,3'-(4,4'-(4,4'-(4,4'-(phenylazanediyl)bis(4,1-phenylene))-bis(1H-1,2,3-triazole-4,1-diyl))bis(2,5-bis(hexyloxy)-4,1-phenylene))bis(2-cyanoacrylic acid)

Guidance literature:: With copper(ll) sulfate pentahydrate; Vitamin C; sodium hydrogencarbonate; In tetrahydrofuran; water; for 8h; Inert atmosphere;
DOI:10.1016/j.dyepig.2011.11.008

Reference yield:

: 916523-19-8
2-(4-bromo-2,5-bis(hexyloxy)phenyl)-1,3-dioxane

: 1360630-00-7
3,3'-(4,4'-(4,4'-(4,4'-(phenylazanediyl)bis(4,1-phenylene))-bis(1H-1,2,3-triazole-4,1-diyl))bis(2,5-bis(hexyloxy)-4,1-phenylene))bis(2-cyanoacrylic acid)

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.67 h / -78 °C

1.2: 4 h / -78 °C

2.1: piperidine / acetonitrile / 12 h / Reflux

3.1: copper(ll) sulfate pentahydrate; Vitamin C; sodium hydrogencarbonate / tetrahydrofuran; water / 8 h / Inert atmosphere

With piperidine; n-butyllithium; copper(ll) sulfate pentahydrate; Vitamin C; sodium hydrogencarbonate; In tetrahydrofuran; hexane; water; acetonitrile; 2.1: Knoevenagel condensation;
DOI:10.1016/j.dyepig.2011.11.008

Reference yield:

: 1360629-97-5
4-azido-2,5-bis(hexyloxy)benzaldehyde

: 1360630-00-7
3,3'-(4,4'-(4,4'-(4,4'-(phenylazanediyl)bis(4,1-phenylene))-bis(1H-1,2,3-triazole-4,1-diyl))bis(2,5-bis(hexyloxy)-4,1-phenylene))bis(2-cyanoacrylic acid)

Guidance literature:: Multi-step reaction with 2 steps

1: piperidine / acetonitrile / 12 h / Reflux

2: copper(ll) sulfate pentahydrate; Vitamin C; sodium hydrogencarbonate / tetrahydrofuran; water / 8 h / Inert atmosphere

With piperidine; copper(ll) sulfate pentahydrate; Vitamin C; sodium hydrogencarbonate; In tetrahydrofuran; water; acetonitrile; 1: Knoevenagel condensation;
DOI:10.1016/j.dyepig.2011.11.008