(p-bromophenyl)(t-butyldimethylsilyloxymethyl)(p-methoxyphenyl)phosphine sulfide

Base Information

Chemical Name:(p-bromophenyl)(t-butyldimethylsilyloxymethyl)(p-methoxyphenyl)phosphine sulfide
CAS No.:1428045-73-1
Molecular Formula:C₂₀H₂₈BrO₂PSSi
Molecular Weight:471.47
Hs Code.:

Synonyms:(p-bromophenyl)(t-butyldimethylsilyloxymethyl)(p-methoxyphenyl)phosphine sulfide

Suppliers and Price of (p-bromophenyl)(t-butyldimethylsilyloxymethyl)(p-methoxyphenyl)phosphine sulfide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (p-bromophenyl)(t-butyldimethylsilyloxymethyl)(p-methoxyphenyl)phosphine sulfide

Chemical Property:

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Technology Process of (p-bromophenyl)(t-butyldimethylsilyloxymethyl)(p-methoxyphenyl)phosphine sulfide

There total 3 articles about (p-bromophenyl)(t-butyldimethylsilyloxymethyl)(p-methoxyphenyl)phosphine sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.9%

: 696-62-8
para-iodoanisole

: 1428045-65-1
(benzoyloxymethyl)(p-bromophenyl)(t-butyldimethylsilyloxymethyl)phosphine sulfide

: 1428045-73-1
(p-bromophenyl)(t-butyldimethylsilyloxymethyl)(p-methoxyphenyl)phosphine sulfide

Guidance literature:: With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium ethanolate; In tetrahydrofuran; at 70 ℃; for 2h;
DOI:10.1021/ol303448j

Reference yield:

: 1420040-42-1
bis(hydroxymethyl)(t-butyldimethylsilyloxymethyl)phosphine sulfide

: 1428045-73-1
(p-bromophenyl)(t-butyldimethylsilyloxymethyl)(p-methoxyphenyl)phosphine sulfide

Guidance literature:: Multi-step reaction with 3 steps

1.1: triethylamine / dichloromethane / 0 °C / Inert atmosphere

1.2: 4 h / 0 °C / Inert atmosphere

2.1: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; 1,8-diazabicyclo[5.4.0]undec-7-ene / toluene / 3 h / 40 °C

3.1: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium ethanolate / tetrahydrofuran / 2 h / 70 °C

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium ethanolate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/ol303448j

Reference yield:

: 1420040-34-1
(benzoyloxymethyl)(t-butyldimethylsilyloxymethyl)(hydroxymethyl)phosphine sulfide

: 1428045-73-1
(p-bromophenyl)(t-butyldimethylsilyloxymethyl)(p-methoxyphenyl)phosphine sulfide

Guidance literature:: Multi-step reaction with 2 steps

1: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; 1,8-diazabicyclo[5.4.0]undec-7-ene / toluene / 3 h / 40 °C

2: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium ethanolate / tetrahydrofuran / 2 h / 70 °C

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium ethanolate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; toluene;
DOI:10.1021/ol303448j