Dicyclidine

Base Information

• Chemical Name: Dicyclidine
• CAS No.: 32809-16-8
• Deprecated CAS: 60120-20-9,68444-90-6
• Molecular Formula: C13H11Cl2NO2
• Molecular Weight: 284.142
• Hs Code.: 29251900
• UNII: EC2FI67U2Y
• Mol file: 32809-16-8.mol

Synonyms:(3,5-dichlorophenyl)-1,2-dimethylcyclopropane-1,2-dicarboximide;dicyclidine;procymidone;Procymidox;S-7131;Sumilex;Sumisclex

Chemical Property of Dicyclidine

Chemical Property:

• Appearance/Colour: Off-White to Pale Beige Solid
• Vapor Pressure: 2.7E-09mmHg at 25°C
• Melting Point: 166-167 ºC
• Refractive Index: 1.643
• Boiling Point: 477.9 ºC at 760 mmHg
• PKA: -2.67±0.60(Predicted)
• Flash Point: 242.8 ºC
• PSA: 37.38000
• Density: 1.502 g/cm³
• LogP: 3.34790
• Storage Temp.: 0-6°C
• Solubility.: Chloroform (Slightly), Ethyl Acetate (Slightly)
• Water Solubility.: 4.5 mg l-1 (25 °C)
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 283.0166840
• Heavy Atom Count: 18
• Complexity: 405

Purity/Quality:

99.9% ^*data from raw suppliers

Procymidox ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC12CC1(C(=O)N(C2=O)C3=CC(=CC(=C3)Cl)Cl)C
• Isomeric SMILES: C[C@]12C[C@]1(C(=O)N(C2=O)C3=CC(=CC(=C3)Cl)Cl)C
• Description: Procymidone is a moderately systemic fungicide. It is used in horticulature as a seed-dressing, pre-harvest spray or post-harvest dip for the control of various fungal diseases, such as grey mold, neck rot, brown rot, blossom blight, and twig wilt. It is applied to vegetables including onions, fruits (including peaches, plums, grapes, stone fruit, strawberries, and cherries), and ornamentals.
• Uses: Systemic agricultural fungicide. Procymidone is a systemic fungcide with both protective and curative activities used to control plant diseases such as fruit rots, grey mould on top fruits, vines and vegetables, and Sclerotinia rot of kidney beans and vegetable crops.

Technology Process of Dicyclidine

There total 1 articles about Dicyclidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ procymidon (32809-16-8)

Guidance literature:

d. Dicarbonsaeuremonoamid, Cycl.;

Reference yield: 82.0%

procymidon (32809-16-8) → C13H10Cl2INO2

Guidance literature:

With iodine; silver trifluoromethanesulfonate; In dichloromethane; at 23 ℃; for 24h;

DOI:10.1021/acs.orglett.1c01530

Reference yield: 67.0%

procymidon (32809-16-8) + N,N-dimethyl acetamide (127-19-5,116057-81-9) → C17H19ClN2O3

Guidance literature:

With 2,6-dimethylpyridine; [2,2]bipyridinyl; nickel(II) bromide dimethoxyethane; at 30 ℃; for 48h; regioselective reaction; Inert atmosphere; Irradiation;

DOI:10.1021/acscatal.0c05694

Downstream raw materials:

3-phenyl-1,5-dimethyl-3-azabicyclo-<3.1.0>hexane-2,4-dione

3,5-Dichloroaniline

Refernces

• 1、 -. "Pyrazolyl benzyl ether derivatives containing a fluoromethoxyimino group and use thereof as pesticides". . . Retrieved 2008/06/13.
• 2、 -. "Iminoacetic acid amides and their use as pest control agents". . . Retrieved 2008/06/13.