1R-(1β,4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-ol

Base Information

Chemical Name:1R-(1β,4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-ol
CAS No.:153165-84-5
Molecular Formula:C₂₂H₂₅N₃O₅
Molecular Weight:411.458
Hs Code.:

Synonyms:1R-(1β,4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-ol

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Chemical Property of 1R-(1β,4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-ol

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Technology Process of 1R-(1β,4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-ol

There total 7 articles about 1R-(1β,4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 153165-82-3
4R-(4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-one

: 153165-84-5
1R-(1β,4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-ol

Guidance literature:: With sodium tetrahydroborate; cerium(III) chloride; In methanol;
DOI:10.1016/S0040-4020(01)87223-9

Reference yield:

: 116003-77-1
2-azido-2-deoxy-4,6-O-(phenylmethylene)methyl-α-D-altropyranoside

: 153165-84-5
1R-(1β,4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-ol

Guidance literature:: Multi-step reaction with 6 steps

1: 87 percent / NBS, CaCO₃ / CCl₄ / 80 °C

2: MeONa / methanol

3: NaH / dimethylformamide

4: 74 percent / Hg(CF₃CO₂)2 / acetone; H₂O / 20 °C

5: 60 percent / mesyl chloride, pyridine / CH₂Cl₂

6: 76 percent / NaBH₄, CeCl₃*7H₂O / methanol

With pyridine; sodium tetrahydroborate; N-Bromosuccinimide; cerium(III) chloride; Hg(II) trifluoroacetate; sodium methylate; sodium hydride; methanesulfonyl chloride; calcium carbonate; In methanol; tetrachloromethane; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1016/S0040-4020(01)87223-9

Reference yield:

: 2746-25-0
p-Methoxybenzyl bromide

: 153165-84-5
1R-(1β,4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1: NaH / dimethylformamide

2: 74 percent / Hg(CF₃CO₂)2 / acetone; H₂O / 20 °C

3: 60 percent / mesyl chloride, pyridine / CH₂Cl₂

4: 76 percent / NaBH₄, CeCl₃*7H₂O / methanol

With pyridine; sodium tetrahydroborate; cerium(III) chloride; Hg(II) trifluoroacetate; sodium hydride; methanesulfonyl chloride; In methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1016/S0040-4020(01)87223-9