carbonyldi-iodo(η5-pentaphenylcyclopentadienyl)rhodium(III)

Base Information

• Chemical Name: carbonyldi-iodo(η5-pentaphenylcyclopentadienyl)rhodium(III)
• CAS No.: 106223-28-3
• Molecular Formula: C₃₆H₂₅I₂ORh
• Molecular Weight: 830.308
• Mol file: 106223-28-3.mol

Synonyms:carbonyldi-iodo(η5-pentaphenylcyclopentadienyl)rhodium(III)

Chemical Property of carbonyldi-iodo(η5-pentaphenylcyclopentadienyl)rhodium(III)

Chemical Property:

Purity/Quality:

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Technology Process of carbonyldi-iodo(η5-pentaphenylcyclopentadienyl)rhodium(III)

There total 1 articles about carbonyldi-iodo(η5-pentaphenylcyclopentadienyl)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(C5(C6H5)5)Rh(CO)2 (102539-06-0) → carbonyldi-iodo(η5-pentaphenylcyclopentadienyl)rhodium(III) (106223-28-3)

Guidance literature:

With iodine; In hexane; toluene; (dry N2); soln of I2 in toluene (10 mL) added to cooled (0 °C) soln. of Rh(CO)2(C5(C6H5)5) in toluene/n-hexane (40 mL/40 mL); standing for 15 min; mother-liquors decanted from resulting crystals; crystals washed (n-hexane) and dried (vac.); elem. anal.;

DOI:10.1039/DT9860001613

Reference yield: 19.0%

carbonyldi-iodo(η5-pentaphenylcyclopentadienyl)rhodium(III) (106223-28-3) → di-μ-carbonyl-bis(η5-pentaphenylcyclopentadienyl)dirhodium(I)

Guidance literature:

With Co(C₅H₅)2; In benzene; (dry N2); Co(C5H5)2 (1.00 mmol) added to stirred suspn. of RhI2(CO)(C5Ph5) (0.51 mmol); mixt. filtered; filtrate concd. (vac.) and added to a column (alumina, n-hexane); elution with benzene; evapn. of the eluate to dryness gave animpure solid;

DOI:10.1039/DT9860001613

upstream raw materials:

(C₅(C₆H₅)5)Rh(CO)2