(3R,4S,5S)-3,4-O-isopropylidene-5-(N-benzyl)-o-nitro-benzensulfon-amino-octa-1,7-diene-3,4-diol

Base Information

Chemical Name:(3R,4S,5S)-3,4-O-isopropylidene-5-(N-benzyl)-o-nitro-benzensulfon-amino-octa-1,7-diene-3,4-diol
CAS No.:483341-78-2
Molecular Formula:C₂₄H₂₈N₂O₆S
Molecular Weight:472.562
Hs Code.:

Synonyms:(3R,4S,5S)-3,4-O-isopropylidene-5-(N-benzyl)-o-nitro-benzensulfon-amino-octa-1,7-diene-3,4-diol

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Chemical Property of (3R,4S,5S)-3,4-O-isopropylidene-5-(N-benzyl)-o-nitro-benzensulfon-amino-octa-1,7-diene-3,4-diol

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Technology Process of (3R,4S,5S)-3,4-O-isopropylidene-5-(N-benzyl)-o-nitro-benzensulfon-amino-octa-1,7-diene-3,4-diol

There total 1 articles about (3R,4S,5S)-3,4-O-isopropylidene-5-(N-benzyl)-o-nitro-benzensulfon-amino-octa-1,7-diene-3,4-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1694-92-4
2-Nitrobenzenesulfonyl chloride

: 301523-39-7
4-benzylamino-1,2,3,4,7,8-hexadeoxy-5,6-O-isopropylidene-D-ribo-oct-1,7-dienitol

: 483341-78-2
(3R,4S,5S)-3,4-O-isopropylidene-5-(N-benzyl)-o-nitro-benzensulfon-amino-octa-1,7-diene-3,4-diol

Guidance literature:: With sodium carbonate; In dichloromethane; at 20 ℃;
DOI:10.1016/j.tet.2004.01.063

Reference yield: 93.0%

: 483341-78-2
(3R,4S,5S)-3,4-O-isopropylidene-5-(N-benzyl)-o-nitro-benzensulfon-amino-octa-1,7-diene-3,4-diol

: 483341-79-3
(1S,2R,6S)-6-(N-benzyl)-o-nitrobenzenesulfonamino-1,2-O-isopropylidene-cyclohex-3-en-1,2-diol

Guidance literature:: With RuCl₂(CHPh)(PPh₃)2;
DOI:10.1016/S0040-4039(02)01364-3

Reference yield:

: 483341-78-2
(3R,4S,5S)-3,4-O-isopropylidene-5-(N-benzyl)-o-nitro-benzensulfon-amino-octa-1,7-diene-3,4-diol

: acridine-9-carboxylic acid-(6-{N-o-nitrobenzenesulfonyl-N-[(1R,4R,6S)-6-(N-benzyl)-6-o-nitrobenzenesulfonamino-cyclohex-2-enol-4-yl]}-aminohexyl)amide

Guidance literature:: Multi-step reaction with 4 steps

1: Cl₂(PPh₃)2Ru=CHPh / CH₂Cl₂ / 20 °C

2: acetic acid; H₂O / 2 h / Heating

3: 98 percent / pyridine / CH₂Cl₂; toluene / 2 h / 0 °C

4: 58 percent / Et₃N; Pd₂(dba)3*CHCl₃; Ph₃P / tetrahydrofuran / 20 °C

With pyridine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; RuCl₂(CHPh)(PPh₃)2; triethylamine; triphenylphosphine; In tetrahydrofuran; dichloromethane; water; acetic acid; toluene;
DOI:10.1016/j.tet.2004.01.063