{Cu(2,9-dimethyl-1,10-phenanthroline)(PPh₃)2}ClO₄

Base Information

• Chemical Name: {Cu(2,9-dimethyl-1,10-phenanthroline)(PPh₃)2}ClO₄
• CAS No.: 161503-28-2
• Molecular Formula: C₅₀H₄₂CuN₂P₂*ClO₄
• Molecular Weight: 895.841
• Mol file: 161503-28-2.mol

Synonyms:{Cu(2,9-dimethyl-1,10-phenanthroline)(PPh₃)2}ClO₄

Chemical Property of {Cu(2,9-dimethyl-1,10-phenanthroline)(PPh₃)2}ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Cu(2,9-dimethyl-1,10-phenanthroline)(PPh₃)2}ClO₄

There total 2 articles about {Cu(2,9-dimethyl-1,10-phenanthroline)(PPh₃)2}ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2.9-dimethyl-1,10-phenanthroline (484-11-7) + tetrakis(acetonitrile)copper(I) perchlorate (14057-91-1) → {Cu(2,9-dimethyl-1,10-phenanthroline)(PPh3)2}ClO4 (161503-28-2)

Guidance literature:

With triphenylphosphine; In ethanol; addn. of the phenanthroline and the phosphine to the Cu-complex in abs. EtOH under N2; elem. anal.;

Reference yield:

tetrakis(acetonitrile)copper(I) perchlorate (14057-91-1) + triphenylphosphine (603-35-0) → {Cu(2,9-dimethyl-1,10-phenanthroline)(PPh3)2}ClO4 (161503-28-2)

Guidance literature:

In ethanol; (N2); mixing the Cu complex and the phosphine in EtOH at room temp. for 1 h; slow evapn. (ice-bath), washing (cold Et2O); elem. anal.;

DOI:10.1039/DT9960001909

Reference yield:

{Cu(2,9-dimethyl-1,10-phenanthroline)(PPh3)2}ClO4 (161503-28-2) + {Co(ethylenediaminetetra-acetate)}K → cobalt(II) ethylenediaminetetraacetate (110169-72-7,110169-73-8,14931-83-0) + {Cu(2,9-dimethyl-1,10-phenanthroline)(PPh3)2}(2+)

Guidance literature:

With triphenylphosphine; In water; acetone; Irradiation (UV/VIS); irradiated at 30 °C under N2 (400-W high-pressure mercury-arc lamp) at 360-400 nm, phosphine was added to suppress the dissociation from the Cu-complex; decrease in {Co(edta)}(1-) concentration was measured spectrophotometrically at its d-d band (539 nm); in the kinetic work the reaction was stopped when the conversion reached 5-7 %; Kinetics;

DOI:10.1039/DT9880001641

upstream raw materials:

2.9-dimethyl-1,10-phenanthroline

tetrakis(acetonitrile)copper(I) perchlorate

triphenylphosphine

Downstream raw materials:

cobalt(II) ethylenediaminetetraacetate

Refernces

• 1、 Sakaki,Koga,Hinokuma,Hashimoto,Ohkubo. "Improvement of the photochemical reactivity of [Cu(dmp)P2]+ (dmp = 2,9-Dimethyl-1,10-phenanthroline; P = tertiary phosphine) by substituting PPh3 with larger phosphines: Application to photoreduction of methylviologen". . p. 1817 - 1819. Retrieved 2008/10/08.