4-Nitrophenyl 6-azido-6-deoxy-alpha-D-mannopyranoside

Base Information

Chemical Name:4-Nitrophenyl 6-azido-6-deoxy-alpha-D-mannopyranoside
CAS No.:211985-65-8
Molecular Formula:C₁₂H₁₄N₄O₇
Molecular Weight:326.266
Hs Code.:
DSSTox Substance ID:DTXSID801231381

Synonyms:DTXSID801231381;4-Nitrophenyl 6-azido-6-deoxy-alpha-D-mannopyranoside;211985-65-8

Suppliers and Price of 4-Nitrophenyl 6-azido-6-deoxy-alpha-D-mannopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-Nitrophenyl 6-azido-6-deoxy-alpha-D-mannopyranoside

Chemical Property:

XLogP3:0.6
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:9
Rotatable Bond Count:4
Exact Mass:326.08624880
Heavy Atom Count:23
Complexity:459

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC(=CC=C1[N+](=O)[O-])OC2C(C(C(C(O2)CN=[N+]=[N-])O)O)O
Isomeric SMILES:C1=CC(=CC=C1[N+](=O)[O-])O[C@@H]2[C@H]([C@H]([C@@H]([C@H](O2)CN=[N+]=[N-])O)O)O

Technology Process of 4-Nitrophenyl 6-azido-6-deoxy-alpha-D-mannopyranoside

There total 2 articles about 4-Nitrophenyl 6-azido-6-deoxy-alpha-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 211985-64-7
Toluene-4-sulfonic acid (2R,3S,4S,5S,6R)-3,4,5-trihydroxy-6-(4-nitro-phenoxy)-tetrahydro-pyran-2-ylmethyl ester

: 211985-65-8
p-nitrophenyl 6-azido-6-deoxy-α-D-mannopyranoside

Guidance literature:: With sodium azide; In N,N-dimethyl-formamide; at 70 ℃; for 8h;
DOI:10.1039/a801985a

Reference yield:

: 10357-27-4
4-nitrophenyl-α-D-mannopyranoside

: 211985-65-8
p-nitrophenyl 6-azido-6-deoxy-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 57 percent / pyridine / 1.) 0 deg C, 1 h, 2.) r.t., 1 h

2: 91 percent / NaN₃ / dimethylformamide / 8 h / 70 °C

With pyridine; sodium azide; In N,N-dimethyl-formamide;
DOI:10.1039/a801985a

Reference yield: 98.0%

: 211985-65-8
p-nitrophenyl 6-azido-6-deoxy-α-D-mannopyranoside

: p-Nitrophenyl 6-amino-6-deoxy-α-D-mannopyranoside

Guidance literature:: p-nitrophenyl 6-azido-6-deoxy-α-D-mannopyranoside; With water; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 0.5h;

With water; silica gel; In tetrahydrofuran; at 45 ℃; for 12h; Further stages.;
DOI:10.1039/b009786l