(biphenyl)manganese tricarbonyl hexafluorophosphate

Base Information

Chemical Name:(biphenyl)manganese tricarbonyl hexafluorophosphate
CAS No.:90553-72-3
Molecular Formula:C₁₅H₁₀MnO₃*F₆P
Molecular Weight:438.145
Hs Code.:

Synonyms:(biphenyl)manganese tricarbonyl hexafluorophosphate

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Chemical Property of (biphenyl)manganese tricarbonyl hexafluorophosphate

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Technology Process of (biphenyl)manganese tricarbonyl hexafluorophosphate

There total 1 articles about (biphenyl)manganese tricarbonyl hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.7%

: ammonium hexafluorophosphate

: 14516-54-2
bromopentacarbonylmanganese(I)

: 92-52-4,1594-86-1
biphenyl

: 90553-72-3
(biphenyl)manganese tricarbonyl hexafluorophosphate

Guidance literature:: With aluminium trichloride; In octane; under N2 at. Mn(CO)5Br and anhyd. AlCl3 heated at 100°C with biphenyl in octane for 16 h, soln. cooled to 0°C, ice water added dropwise with stirring, aq. layer washed with isopentane and treated with aq. NH4PF6 at 0°C;; product taken up into acetone and filtered, solid dried in vacuo; elem. anal.;
DOI:10.1021/ja00327a015

Reference yield:

: 90553-72-3
(biphenyl)manganese tricarbonyl hexafluorophosphate

: 1-phenylcyclohexadienylmanganese tricarbonyl

: 2-phenylcyclohexadienylmanganese tricarbonyl

: 3-phenylcyclohexadienylmanganese tricarbonyl

Guidance literature:: With potassium tri(isopropoxy)borohydride; In tetrahydrofuran; under N2 atm.; stirred suspn. ((C6H5)2)Mn(CO)3PF6 in THF treated with 1 equiv. K((PriO)3BH) in THF at room temp.;; after 20 min NaCl brine added dropwise at 0°C, organic layer dried with Na2SO4, solvent removed, product taken up into isopentane and chromed. on neutral alumina, with pentane as eluent, product recrystd. from min. amt. isopentane at -78°C;
DOI:10.1021/ja00327a015

Reference yield:

: 90553-72-3
(biphenyl)manganese tricarbonyl hexafluorophosphate

: 4-phenylcyclohexenylmanganese tricarbonyl

: 3-phenylcyclohexenylmanganese tricarbonyl

: 2-phenylcyclohexenylmanganese tricarbonyl

Guidance literature:: With potassium tri(isopropoxy)borohydride; In tetrahydrofuran; under N2 atm. to a stirred suspn. of (C6H5OCH3)Mn(CO)3PF6 in THF is added 3,5 equiv. of K((PriO)3BH) in THF and refluxed for 15 min, soln. cooled to 0°C;; NaCl brine added, organic layer dried with Na2SO4, solvent removed, oil extd.into isopentane and chromd. on basic alumina with isopentane as eluent;;
DOI:10.1021/ja00327a015