HN₃(2,6-Mes₂C₆H₃)[2-(2,4,6-iPr₃C₆H₂)C₆H₄]

Base Information

Chemical Name:HN₃(2,6-Mes₂C₆H₃)[2-(2,4,6-iPr₃C₆H₂)C₆H₄]
CAS No.:869383-17-5
Molecular Formula:C₄₅H₅₃N₃
Molecular Weight:635.936
Hs Code.:

HN<sub>3</sub>(2,6-Mes<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)[2-(2,4,6-iPr<sub>3</sub>C<sub>6</sub>H<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>]

Synonyms:HN₃(2,6-Mes₂C₆H₃)[2-(2,4,6-iPr₃C₆H₂)C₆H₄]

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Chemical Property of HN₃(2,6-Mes₂C₆H₃)[2-(2,4,6-iPr₃C₆H₂)C₆H₄]

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Technology Process of HN₃(2,6-Mes₂C₆H₃)[2-(2,4,6-iPr₃C₆H₂)C₆H₄]

There total 1 articles about HN₃(2,6-Mes₂C₆H₃)[2-(2,4,6-iPr₃C₆H₂)C₆H₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 477933-79-2
2'-azido-2,4,6,2'',4'',6''-hexamethyl-[1,1';3',1'']terphenyl

: 409061-67-2
2'-iodo-2,4,6-triisopropyl-1,1'-biphenyl

: 869383-17-5
HN₃(2,6-Mes₂C₆H₃)[2-(2,4,6-iPr₃C₆H₂)C₆H₄]

Guidance literature:: 2'-iodo-2,4,6-triisopropyl-1,1'-biphenyl; With n-butyllithium; In diethyl ether; hexane; at 0 ℃; for 2h;

2'-azido-2,4,6,2'',4'',6''-hexamethyl-[1,1';3',1'']terphenyl; In diethyl ether; hexane; at 0 - 20 ℃;
DOI:10.1002/anie.200501494

Reference yield: 90.0%

: 869383-17-5
HN₃(2,6-Mes₂C₆H₃)[2-(2,4,6-iPr₃C₆H₂)C₆H₄]

: mercury(II) iodide

: 1241550-76-4,1241550-77-5
iodo-[[[N'-2-(2',4',6'-triisopropyl)biphenyl]-(N'''-2,4,6,2'',4'',6''-hexamethyl-1,1':3',1''-terphen-2'-yl)]triazenido-N']mercury

Guidance literature:: With nBuLi; In diethyl ether; hexane; byproducts: LiI, nBuH; under Ar, using Schlenk technique; to stirred cooled soln. of triazene deriv. in ethyl ether added n-BuLi in hexane; stirred for 30 min; HgCl2 added, stirred at ambient temp. for 4 h; volatile materials removed under reduced pressure; solid extd. with n-heptane; LiI separated by centrifugation, filtrate concd., cooled at -20°C;
DOI:10.1002/zaac.200900482

Reference yield: 84.0%

: 869383-17-5
HN₃(2,6-Mes₂C₆H₃)[2-(2,4,6-iPr₃C₆H₂)C₆H₄]

: mercury dichloride

: 1241550-72-0
chloro-[[[N'-2-(2',4',6'-triisopropyl)biphenyl]-(N'''-2,5,6,2'',4'',6''-hexamethyl-1,1':3',1''terphen-2'-yl)]triazenido-N']mercury

Guidance literature:: With nBuLi; In diethyl ether; hexane; byproducts: LiCl, nBuH; under Ar, using Schlenk technique; to stirred cooled soln. of triazene deriv. in ethyl ether added n-BuLi in hexane; stirred for 30 min; HgCl2 added, stirred at ambient temp. for 4 h; volatile materials removed under reduced pressure; solid extd. with n-heptane; LiCl separated by centrifugation, filtrate concd., cooled at -20°C;
DOI:10.1002/zaac.200900482