(3S,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine

Base Information

Chemical Name:(3S,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine
CAS No.:204120-60-5
Molecular Formula:C₄₅H₅₅NO₃Si₂
Molecular Weight:714.108
Hs Code.:

Synonyms:(3S,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine

Chemical Property:

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Technology Process of (3S,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine

There total 5 articles about (3S,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 100-46-9
benzylamine

: C₅₂H₆₂O₉S₂Si₂

: (3R,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine

: 204120-60-5
(3S,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine

Guidance literature:: DOI:10.1021/jo971995f

Reference yield: 22.4%

: 100-46-9
benzylamine

: C₅₂H₆₂O₉S₂Si₂

: (3R,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine

: 204120-60-5
(3S,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine

: (3R,5R)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine

Guidance literature:: at 90 ℃; Title compound not separated from byproducts;
DOI:10.1021/jo971995f

Reference yield:

: 557-40-4
Allyl ether

: 204120-60-5
(3S,5S)-4-Benzyl-3,5-bis-(tert-butyl-diphenyl-silanyloxymethyl)-morpholine

Guidance literature:: Multi-step reaction with 4 steps

1: AD-mix (K₂OsO₂(OH)4, K₃Fe(CN)6, (DHQ)2-AQN as ligand) / 96 h

2: imidazole / dimethylformamide

3: Et₃N, DMAP / CH₂Cl₂

4: 38 percent

With 1H-imidazole; dmap; AD-mix (K₂OsO₂(OH)4, K₃Fe(CN)6, (DHQ)2-AQN as ligand); triethylamine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo971995f