[Fe(N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine)]⁽²⁺⁾

Base Information

• Chemical Name: [Fe(N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine)]⁽²⁺⁾
• CAS No.: 312321-65-6
• Molecular Formula: C₂₇H₂₉N₅*Fe
• Molecular Weight: 479.408
• Mol file: 312321-65-6.mol

Synonyms:[Fe(N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine)]⁽²⁺⁾

Chemical Property of [Fe(N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine)]⁽²⁺⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine)]⁽²⁺⁾

There total 2 articles about [Fe(N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine)]⁽²⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[FeO(N,N-bis(N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2diamine)](2+) → [Fe(N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine)](2+) (312321-65-6)

Guidance literature:

With methyl-phenyl-thioether; In acetonitrile; byproducts: C6H5S(O)CH3; thianizole added at -20°C; not isolated; monitored by UV spectroscopy; Kinetics;

DOI:10.1021/ja055709q

Reference yield:

(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)iron(II) (135284-80-9) + N,N’,N’-tris(2-pyridylmethyl)-1,2-diaminoethane (862672-44-4,862672-43-3,862672-45-5,423720-04-1) → oxido(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)iron(IV) (905575-09-9,850532-78-4) + [Fe(N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine)](2+) (312321-65-6)

Guidance literature:

In acetonitrile; at 25°C; detd. by UV-Vis spectroscopy;

DOI:10.1002/anie.200504422

Reference yield:

[Fe(II)(N-benzyl-N,N',N'-tris(2-pyridylmethyl)-1,2-diaminoethane)](2+) (312321-65-6) + oxygen (80937-33-3) → [Fe(III)(N-benzyl-N,N',N'-tris(2-pyridylmethyl)-1,2-diaminoethane)(hydroperoxo)](2+) (243458-48-2)

Guidance literature:

With perchloric acid; 1-Benzyl-1,4-dihydronicotinamide; In acetonitrile; addn. of nicotinamide deriv. and HClO4 to a soln. of iron complex in MeCN in the presence of O2;

DOI:10.1021/ja905691f

upstream raw materials:

(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)iron(II)

N,N’,N’-tris(2-pyridylmethyl)-1,2-diaminoethane

Downstream raw materials:

[Fe(III)(N-benzyl-N,N',N'-tris(2-pyridylmethyl)-1,2-diaminoethane)(hydroperoxo)]⁽²⁺⁾