m-tolyl 2-aminobenzoate

Base Information

• Chemical Name: m-tolyl 2-aminobenzoate
• CAS No.: 93985-57-0
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 227.263
• Mol file: 93985-57-0.mol

Synonyms:m-tolyl 2-aminobenzoate

Chemical Property of m-tolyl 2-aminobenzoate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of m-tolyl 2-aminobenzoate

There total 4 articles about m-tolyl 2-aminobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

isatoic anhydride (118-48-9) + m-tolylboronic acid (17933-03-8) → m-tolyl 2-aminobenzoate (93985-57-0)

Guidance literature:

With N-methylcyclohexylamine; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; oxygen; bis[2-(diphenylphosphino)phenyl] ether; In tetrahydrofuran; at 60 ℃; for 24h;

DOI:10.1021/ol202609a

Reference yield: 80.0%

isatoic anhydride (118-48-9) + 4-methylsalicylaldehyde (698-27-1) → m-tolyl 2-aminobenzoate (93985-57-0)

Guidance literature:

With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; cesium acetate; In toluene; at 95 ℃; for 7h;

DOI:10.1039/d1ob00027f

Reference yield: 68.0%

isatoic anhydride (118-48-9) + 3-methyl-phenol (108-39-4) → m-tolyl 2-aminobenzoate (93985-57-0)

Guidance literature:

With sodium hydroxide; In 1,4-dioxane; for 0.5h; Heating;

upstream raw materials:

isatoic anhydride

3-methyl-phenol

m-tolylboronic acid

4-methylsalicylaldehyde

Downstream raw materials:

C₂₀H₁₇N₃O₂