Acetic acid (1S,2R,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-6-oxo-cyclohexyl ester

Base Information

Chemical Name:Acetic acid (1S,2R,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-6-oxo-cyclohexyl ester
CAS No.:222545-15-5
Molecular Formula:C₂₄H₂₈O₈
Molecular Weight:444.482
Hs Code.:

Synonyms:Acetic acid (1S,2R,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-6-oxo-cyclohexyl ester

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Chemical Property of Acetic acid (1S,2R,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-6-oxo-cyclohexyl ester

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Technology Process of Acetic acid (1S,2R,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-6-oxo-cyclohexyl ester

There total 4 articles about Acetic acid (1S,2R,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-6-oxo-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 824-94-2
p-methoxybenzyl chloride

: 222545-15-5
Acetic acid (1S,2R,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-6-oxo-cyclohexyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) NaH / 1.) DMF, 0 deg C, 1 h, 2.) room temperature, 20 h

2: 89 percent / AcOH / H₂O / 2 h / 60 °C

3: 93 percent / PPh₃, imidazole, I₂ / toluene / 5 h / Ambient temperature

4: 1.) t-BuOK, 2.) pyridine / 1.) THF, room temperature, 23 h, 2.) room temperature, 3 h

5: 100 percent / Hg(OCOCF₃)2 / acetone; H₂O / 15 h / Ambient temperature

With pyridine; 1H-imidazole; potassium tert-butylate; iodine; mercury(II) trifluoroacetate; sodium hydride; acetic acid; triphenylphosphine; In water; acetone; toluene;
DOI:10.1016/S0040-4020(99)00004-6

Reference yield:

: 222545-13-3
methyl 2,3-di-O-(4-methoxyphenylmethyl)-α-D-glucopyranoside

: 222545-15-5
Acetic acid (1S,2R,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-6-oxo-cyclohexyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / PPh₃, imidazole, I₂ / toluene / 5 h / Ambient temperature

2: 1.) t-BuOK, 2.) pyridine / 1.) THF, room temperature, 23 h, 2.) room temperature, 3 h

3: 100 percent / Hg(OCOCF₃)2 / acetone; H₂O / 15 h / Ambient temperature

With pyridine; 1H-imidazole; potassium tert-butylate; iodine; mercury(II) trifluoroacetate; triphenylphosphine; In water; acetone; toluene;
DOI:10.1016/S0040-4020(99)00004-6

Reference yield:

: 199918-03-1
methyl 2,3-bis-O-(4-methoxybenzyl)-4,6-O-phenylmethylene-α-D-glucopyranoside

: 222545-15-5
Acetic acid (1S,2R,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-6-oxo-cyclohexyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 89 percent / AcOH / H₂O / 2 h / 60 °C

2: 93 percent / PPh₃, imidazole, I₂ / toluene / 5 h / Ambient temperature

3: 1.) t-BuOK, 2.) pyridine / 1.) THF, room temperature, 23 h, 2.) room temperature, 3 h

4: 100 percent / Hg(OCOCF₃)2 / acetone; H₂O / 15 h / Ambient temperature

With pyridine; 1H-imidazole; potassium tert-butylate; iodine; mercury(II) trifluoroacetate; acetic acid; triphenylphosphine; In water; acetone; toluene;
DOI:10.1016/S0040-4020(99)00004-6