(+)-2-chloro-3-[(S)-4-methylbenzenesulfinyl]cyclohexa-2,5-diene-1,4-dione

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Chemical Name:(+)-2-chloro-3-[(S)-4-methylbenzenesulfinyl]cyclohexa-2,5-diene-1,4-dione
CAS No.:161953-64-6
Molecular Formula:C₁₃H₉ClO₃S
Molecular Weight:280.732
Hs Code.:

Synonyms:(+)-2-chloro-3-[(S)-4-methylbenzenesulfinyl]cyclohexa-2,5-diene-1,4-dione

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Chemical Property of (+)-2-chloro-3-[(S)-4-methylbenzenesulfinyl]cyclohexa-2,5-diene-1,4-dione

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Technology Process of (+)-2-chloro-3-[(S)-4-methylbenzenesulfinyl]cyclohexa-2,5-diene-1,4-dione

There total 5 articles about (+)-2-chloro-3-[(S)-4-methylbenzenesulfinyl]cyclohexa-2,5-diene-1,4-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 161953-62-4
(-)-2-chloro-3-[(S)-4-methylbenzenesulfinyl]benzene-1,4-diol

: 161953-64-6
(+)-2-chloro-3-[(S)-4-methylbenzenesulfinyl]cyclohexa-2,5-diene-1,4-dione

Guidance literature:: With ammonium cerium (IV) nitrate; In water; acetonitrile; for 1h;
DOI:10.1039/c6md00392c

Reference yield:

: 134281-83-7
(+)-(S)-2-(p-tolylsulfinyl)cyclohexa-2,5-diene-1,4-dione

: 161953-64-6
(+)-2-chloro-3-[(S)-4-methylbenzenesulfinyl]cyclohexa-2,5-diene-1,4-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / TiCl₄ / CH₂Cl₂

2: 88 percent / cerium (IV) ammonium nitrate

With ammonium cerium(IV) nitrate; titanium tetrachloride; In dichloromethane;
DOI:10.1016/0040-4039(94)88379-3

Reference yield:

: 134281-63-3
(S)-(-)-1,4-dimethoxy-2-(p-tolylsulfinyl)benzene

: 161953-64-6
(+)-2-chloro-3-[(S)-4-methylbenzenesulfinyl]cyclohexa-2,5-diene-1,4-dione

Guidance literature:: Multi-step reaction with 3 steps

1.1: ammonium cerium (IV) nitrate / water; acetonitrile / 1 h / 20 °C

2.1: titanium tetrachloride / dichloromethane / 0 - 20 °C / Inert atmosphere

2.2: 5 h

3.1: ammonium cerium (IV) nitrate / water; acetonitrile / 1 h

With ammonium cerium (IV) nitrate; titanium tetrachloride; In dichloromethane; water; acetonitrile;
DOI:10.1039/c6md00392c