methyl 4-(N-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl-carbamoyl)benzoate

Base Information

• Chemical Name: methyl 4-(N-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl-carbamoyl)benzoate
• CAS No.: 896730-91-9
• Molecular Formula: C₂₃H₂₇NO₁₂
• Molecular Weight: 509.467
• Mol file: 896730-91-9.mol

Synonyms:methyl 4-(N-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl-carbamoyl)benzoate

Chemical Property of methyl 4-(N-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl-carbamoyl)benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 4-(N-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl-carbamoyl)benzoate

There total 2 articles about methyl 4-(N-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl-carbamoyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-azido-1-deoxy-β-D-glucopyranoside tetraacetate (13992-25-1) → methyl 4-(N-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl-carbamoyl)benzoate (896730-91-9)

Guidance literature:

Multi-step reaction with 2 steps

1: CH₂Cl₂ / 20 °C

2: 0.60 g / CH₂Cl₂

In dichloromethane;

DOI:10.1016/j.carres.2006.03.002

Reference yield:

Monomethyl terephthalate (1679-64-7) + C17H28NO9P (353264-31-0) → methyl 4-(N-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl-carbamoyl)benzoate (896730-91-9)

Guidance literature:

In dichloromethane;

DOI:10.1016/j.carres.2006.03.002

Reference yield: 91.0%

methyl 4-(N-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl-carbamoyl)benzoate (896730-91-9) → methyl 4-(N-β-D-glucopyranosyl-carbamoyl)benzoate (896730-94-2)

Guidance literature:

With sodium methylate; In methanol; at 20 ℃;

DOI:10.1016/j.carres.2006.03.002

upstream raw materials:

Monomethyl terephthalate

C₁₇H₂₈NO₉P

1-azido-1-deoxy-β-D-glucopyranoside tetraacetate

Downstream raw materials:

methyl 4-(N-β-D-glucopyranosyl-carbamoyl)benzoate