3-Benzyloxy-4-((R)-2-hydroxy-4-trimethylsilanyl-but-3-ynyl)-5-nitro-benzoic acid methyl ester

Base Information

Chemical Name:3-Benzyloxy-4-((R)-2-hydroxy-4-trimethylsilanyl-but-3-ynyl)-5-nitro-benzoic acid methyl ester
CAS No.:704906-38-7
Molecular Formula:C₂₂H₂₅NO₆Si
Molecular Weight:427.529
Hs Code.:

Synonyms:3-Benzyloxy-4-((R)-2-hydroxy-4-trimethylsilanyl-but-3-ynyl)-5-nitro-benzoic acid methyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-Benzyloxy-4-((R)-2-hydroxy-4-trimethylsilanyl-but-3-ynyl)-5-nitro-benzoic acid methyl ester

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Technology Process of 3-Benzyloxy-4-((R)-2-hydroxy-4-trimethylsilanyl-but-3-ynyl)-5-nitro-benzoic acid methyl ester

There total 4 articles about 3-Benzyloxy-4-((R)-2-hydroxy-4-trimethylsilanyl-but-3-ynyl)-5-nitro-benzoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1066-54-2
trimethylsilylacetylene

: 704906-34-3
3-benzoyloxy-5-nitro-4-(2-oxoethyl)benzoic acid methyl ester

: 704906-38-7
3-Benzyloxy-4-((R)-2-hydroxy-4-trimethylsilanyl-but-3-ynyl)-5-nitro-benzoic acid methyl ester

Guidance literature:: With (1S,2R)-(+)-N-methylephedrine; zinc trifluoromethanesulfonate; triethylamine; In toluene; at 20 ℃; for 17.5h;
DOI:10.1021/ol049583y

Reference yield: 89.0%

: C₁₆H₁₃NO₆

: 1066-54-2
trimethylsilylacetylene

: 704906-38-7
3-Benzyloxy-4-((R)-2-hydroxy-4-trimethylsilanyl-but-3-ynyl)-5-nitro-benzoic acid methyl ester

Guidance literature:: With (-)-N-methylephedrine; zinc trifluoromethanesulfonate; triethylamine; In toluene; at 20 ℃; for 18.25h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/chem.201003489