(S)-(η6-5-bromo-8-phenylnaphthalene)tricarbonylchromium

Base Information

• Chemical Name: (S)-(η6-5-bromo-8-phenylnaphthalene)tricarbonylchromium
• CAS No.: 1290035-59-4
• Molecular Formula: C₁₉H₁₁BrCrO₃
• Molecular Weight: 419.195
• Mol file: 1290035-59-4.mol

Synonyms:(S)-(η6-5-bromo-8-phenylnaphthalene)tricarbonylchromium

Chemical Property of (S)-(η6-5-bromo-8-phenylnaphthalene)tricarbonylchromium

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (S)-(η6-5-bromo-8-phenylnaphthalene)tricarbonylchromium

There total 1 articles about (S)-(η6-5-bromo-8-phenylnaphthalene)tricarbonylchromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(η6-5,8-dibromonaphthalene)tricarbonylchromium (882746-92-1) + phenylboronic acid (98-80-6) → (η6-5,8-diphenylnaphthalene)tricarbonylchromium (1290035-60-7) + (S)-(η6-5-bromo-8-phenylnaphthalene)tricarbonylchromium (1290035-59-4)

Guidance literature:

With catalyst:Pd(dba)2/(C₁₀H₅C₆H₅O)2PN(CHCH₃C₆H₅)/KF; In toluene; Cr complex reacted with boronic acid in toluene catalyzed by Pd(dba)2/(C10H5C6H5O)2PN(CHCH3C6H5)2/KF system at 0-10°C for 4-20 h;

DOI:10.1039/c1cc10347d

Reference yield: 75.0%

sodium cyanotrihydroborate + (S)-(η6-5-bromo-8-phenylnaphthalene)tricarbonylchromium (1290035-59-4) → (CO)3CrC10H7C6H5 (952608-79-6,181135-35-3,1290597-09-9)

Guidance literature:

With catalyst:Pd(dba)2/(tBu)3PHBF₄; In N,N-dimethyl-formamide; Cr complex reacted with NaBH3CN in DMF catalyzed by Pd(dba)2/(t-Bu)3PHBF4 system at room temp. for 1 h;

DOI:10.1039/c1cc10347d

upstream raw materials:

(η6-5,8-dibromonaphthalene)tricarbonylchromium

phenylboronic acid

Downstream raw materials:

(CO)3CrC₁₀H₇C₆H₅