(2R,3R,5R,6R)-3-(tert-butyldiphenylsilanyloxymethyl)-5,6-dihydroxy-2-hydroxymethylcyclohexanone

Base Information

Chemical Name:(2R,3R,5R,6R)-3-(tert-butyldiphenylsilanyloxymethyl)-5,6-dihydroxy-2-hydroxymethylcyclohexanone
CAS No.:1256356-00-9
Molecular Formula:C₂₄H₃₂O₅Si
Molecular Weight:428.601
Hs Code.:

Synonyms:(2R,3R,5R,6R)-3-(tert-butyldiphenylsilanyloxymethyl)-5,6-dihydroxy-2-hydroxymethylcyclohexanone

Suppliers and Price of (2R,3R,5R,6R)-3-(tert-butyldiphenylsilanyloxymethyl)-5,6-dihydroxy-2-hydroxymethylcyclohexanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2R,3R,5R,6R)-3-(tert-butyldiphenylsilanyloxymethyl)-5,6-dihydroxy-2-hydroxymethylcyclohexanone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2R,3R,5R,6R)-3-(tert-butyldiphenylsilanyloxymethyl)-5,6-dihydroxy-2-hydroxymethylcyclohexanone

There total 1 articles about (2R,3R,5R,6R)-3-(tert-butyldiphenylsilanyloxymethyl)-5,6-dihydroxy-2-hydroxymethylcyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 1256355-99-3
(5R,6R)-5-(tert-butyldiphenylsilanyloxymethyl)-6-hydroxymethylcyclohex-2-enone

: 1256356-00-9
(2R,3R,5R,6R)-3-(tert-butyldiphenylsilanyloxymethyl)-5,6-dihydroxy-2-hydroxymethylcyclohexanone

Guidance literature:: With methanesulfonamide; AD-mix-β; water; In tert-butyl alcohol; at 20 ℃; for 24h; stereoselective reaction;
DOI:10.1016/j.tetasy.2010.07.033

Reference yield: 90.0%

: 1256356-00-9
(2R,3R,5R,6R)-3-(tert-butyldiphenylsilanyloxymethyl)-5,6-dihydroxy-2-hydroxymethylcyclohexanone

: 1334018-80-2
C₂₄H₃₄O₅Si

Guidance literature:: (2R,3R,5R,6R)-3-(tert-butyldiphenylsilanyloxymethyl)-5,6-dihydroxy-2-hydroxymethylcyclohexanone; With sodium tetrahydroborate; In methanol;

With water; diastereospecific reaction;
DOI:10.1016/j.tetasy.2010.07.033