p-iodophenyl 3-O-allyl-2-O-propionyl-6-O-(m-trifluoromethyl)benzenesulfonyl-β-D-glucopyranoside

Base Information

Chemical Name:p-iodophenyl 3-O-allyl-2-O-propionyl-6-O-(m-trifluoromethyl)benzenesulfonyl-β-D-glucopyranoside
CAS No.:272122-69-7
Molecular Formula:C₂₅H₂₆F₃IO₉S
Molecular Weight:686.442
Hs Code.:

Synonyms:p-iodophenyl 3-O-allyl-2-O-propionyl-6-O-(m-trifluoromethyl)benzenesulfonyl-β-D-glucopyranoside

Suppliers and Price of p-iodophenyl 3-O-allyl-2-O-propionyl-6-O-(m-trifluoromethyl)benzenesulfonyl-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of p-iodophenyl 3-O-allyl-2-O-propionyl-6-O-(m-trifluoromethyl)benzenesulfonyl-β-D-glucopyranoside

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Technology Process of p-iodophenyl 3-O-allyl-2-O-propionyl-6-O-(m-trifluoromethyl)benzenesulfonyl-β-D-glucopyranoside

There total 11 articles about p-iodophenyl 3-O-allyl-2-O-propionyl-6-O-(m-trifluoromethyl)benzenesulfonyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 777-44-6
3-(Trifluoromethyl)benzenesulfonyl chloride

: 596847-23-3
4-iodophenyl 3-O-allyl-2-O-propionyl-β-D-glucopyranoside

: 272122-69-7
p-iodophenyl 3-O-allyl-2-O-propionyl-6-O-(m-trifluoromethyl)benzenesulfonyl-β-D-glucopyranoside

Guidance literature:: With pyridine; dmap; at 0 - 20 ℃;
DOI:10.1021/jm0205853

Reference yield:

: 272123-08-7
p-iodophenyl 3-O-allyl-β-D-glucopyranoside

: 272122-69-7
p-iodophenyl 3-O-allyl-2-O-propionyl-6-O-(m-trifluoromethyl)benzenesulfonyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 434 mg / HBF₄ / dimethylformamide; diethyl ether / 20 °C

2: 96 percent / pyridine / 20 °C

3: 98 percent / aq. TFA / tetrahydrofuran / 2 h / 85 °C

4: 95 percent / pyridine; DMAP / 0 - 20 °C

With pyridine; dmap; tetrafluoroboric acid; trifluoroacetic acid; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jm0205853

Reference yield:

: 596847-04-0
p-iodophenyl 2,4,6-tri-O-acetyl-3-O-allyl-β-D-glucopyranoside

: 272122-69-7
p-iodophenyl 3-O-allyl-2-O-propionyl-6-O-(m-trifluoromethyl)benzenesulfonyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: NaOMe; MeOH / 2 h / pH 9

2: 434 mg / HBF₄ / dimethylformamide; diethyl ether / 20 °C

3: 96 percent / pyridine / 20 °C

4: 98 percent / aq. TFA / tetrahydrofuran / 2 h / 85 °C

5: 95 percent / pyridine; DMAP / 0 - 20 °C

With pyridine; methanol; dmap; tetrafluoroboric acid; sodium methylate; trifluoroacetic acid; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jm0205853