[bis(triphenylphosphoranylidene)ammonium][(NO)2Fe(OPh)2]

Base Information

• Chemical Name: [bis(triphenylphosphoranylidene)ammonium][(NO)2Fe(OPh)2]
• CAS No.: 1190714-61-4
• Molecular Formula: C₁₂H₁₀FeN₂O₄*C₃₆H₃₀NP₂
• Molecular Weight: 840.658
• Mol file: 1190714-61-4.mol

Synonyms:[bis(triphenylphosphoranylidene)ammonium][(NO)2Fe(OPh)2]

Chemical Property of [bis(triphenylphosphoranylidene)ammonium][(NO)2Fe(OPh)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [bis(triphenylphosphoranylidene)ammonium][(NO)2Fe(OPh)2]

There total 3 articles about [bis(triphenylphosphoranylidene)ammonium][(NO)2Fe(OPh)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[bis(triphenylphosphoranylidene)ammonium][Fe(nitrito-O)2(NO)2] (1190714-59-0) + sodium phenoxide (139-02-6) → [bis(triphenylphosphoranylidene)ammonium][(NO)2Fe(OPh)2] (1190714-61-4)

Guidance literature:

In tetrahydrofuran; (N2) soln. Fe complex in THF was stirred for 5 min at room temp.; soln. was filtered through Celite and concd. in vacuo, Et2O and hexane were added; elem. anal.;

DOI:10.1021/ic901675p

Reference yield: 75.0%

[bis(triphenylphosphoranylidene)ammonium]2[Fe(μ-OPh)(NO)2]2*CH3CN → [bis(triphenylphosphoranylidene)ammonium][(NO)2Fe(OPh)2] (1190714-61-4)

Guidance literature:

With [(C₅H₅)2Fe]BF₄; KOPh; 18-crown-6; In acetonitrile; (N2); Schlenk technique; Fe-NO complex (1 equiv.) and Fe-BF4 (2 equiv.) complex were dissolved in MeCN; stirred at 0°C for 5 min; transferred to mixt. of KOPh (2 equiv.) and crown ether (2 equiv.); stirred for5 min; IR monitoring; dried (vac.); redissolved in THF; filtered through Celite; hexane added;

DOI:10.1021/ic202332d

Reference yield:

bis(triphenylphosphoranylidene)ammonium nitrite → [bis(triphenylphosphoranylidene)ammonium][(NO)2Fe(OPh)2] (1190714-61-4)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: tetrahydrofuran

In tetrahydrofuran;

DOI:10.1021/ic901675p

upstream raw materials:

[bis(triphenylphosphoranylidene)ammonium][Fe(nitrito-O)2(NO)2]

sodium phenoxide

Downstream raw materials:

[PPN][(NO)2Fe(OPh)(SC₄H₃S)]

[PPN][(NO)2Fe(OC₆H₄-p-F)2]

[PPN][(NO)2Fe(imidazolate)2]