dimethyl 2,7-bis({4-[(4-ethynylphenyl)ethynyl]phenyl}ethynyl)-4a'H-spiro[fluorene-9,5'-pyrrolo[1,2-b]pyridazine]-6',7'-dicarboxylate

Base Information

Chemical Name:dimethyl 2,7-bis({4-[(4-ethynylphenyl)ethynyl]phenyl}ethynyl)-4a'H-spiro[fluorene-9,5'-pyrrolo[1,2-b]pyridazine]-6',7'-dicarboxylate
CAS No.:1133809-76-3
Molecular Formula:C₅₉H₃₄N₂O₄
Molecular Weight:834.93
Hs Code.:

Synonyms:dimethyl 2,7-bis({4-[(4-ethynylphenyl)ethynyl]phenyl}ethynyl)-4a'H-spiro[fluorene-9,5'-pyrrolo[1,2-b]pyridazine]-6',7'-dicarboxylate

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Chemical Property of dimethyl 2,7-bis({4-[(4-ethynylphenyl)ethynyl]phenyl}ethynyl)-4a'H-spiro[fluorene-9,5'-pyrrolo[1,2-b]pyridazine]-6',7'-dicarboxylate

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Technology Process of dimethyl 2,7-bis({4-[(4-ethynylphenyl)ethynyl]phenyl}ethynyl)-4a'H-spiro[fluorene-9,5'-pyrrolo[1,2-b]pyridazine]-6',7'-dicarboxylate

There total 2 articles about dimethyl 2,7-bis({4-[(4-ethynylphenyl)ethynyl]phenyl}ethynyl)-4a'H-spiro[fluorene-9,5'-pyrrolo[1,2-b]pyridazine]-6',7'-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 1133809-91-2
dimethyl 2,7-bis((4-((4-((trimethylsilyl)ethynyl)phenyl)ethynyl)phenyl)ethynyl)-4a'H-spiro[fluorene-9,5'-pyrrolo[1,2-b]pyridazine]-6',7'-dicarboxylate

: 1133809-76-3
dimethyl 2,7-bis({4-[(4-ethynylphenyl)ethynyl]phenyl}ethynyl)-4a'H-spiro[fluorene-9,5'-pyrrolo[1,2-b]pyridazine]-6',7'-dicarboxylate

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;
DOI:10.1016/j.tet.2008.12.047

Reference yield: 16.0%

: 289-80-5
1,2-diazine

: 1133809-66-1
C₅₅H₃₀O₄

: 1133809-76-3
dimethyl 2,7-bis({4-[(4-ethynylphenyl)ethynyl]phenyl}ethynyl)-4a'H-spiro[fluorene-9,5'-pyrrolo[1,2-b]pyridazine]-6',7'-dicarboxylate

Guidance literature:: In diethyl ether; at 20 ℃; for 24h; Inert atmosphere; Darkness;
DOI:10.1016/j.tet.2008.12.047

Reference yield: 60.0%

: 1133809-76-3
dimethyl 2,7-bis({4-[(4-ethynylphenyl)ethynyl]phenyl}ethynyl)-4a'H-spiro[fluorene-9,5'-pyrrolo[1,2-b]pyridazine]-6',7'-dicarboxylate

: 69746-43-6
1-iodo-4-thioacetylbenzene

: 1133810-06-6
C₆₇H₄₀N₂O₅S

Guidance literature:: With copper(l) iodide; N-ethyl-N,N-diisopropylamine; triphenylphosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; at 40 ℃; for 3h; Inert atmosphere;
DOI:10.1016/j.tet.2008.12.047