3-[(1S,3R,4S,5R)-5-Acetoxy-3-(2-acetoxy-ethyl)-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

Base Information

Chemical Name:3-[(1S,3R,4S,5R)-5-Acetoxy-3-(2-acetoxy-ethyl)-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester
CAS No.:123886-99-7
Molecular Formula:C₂₀H₃₄O₆
Molecular Weight:370.486
Hs Code.:

Synonyms:3-[(1S,3R,4S,5R)-5-Acetoxy-3-(2-acetoxy-ethyl)-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

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Chemical Property of 3-[(1S,3R,4S,5R)-5-Acetoxy-3-(2-acetoxy-ethyl)-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

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Technology Process of 3-[(1S,3R,4S,5R)-5-Acetoxy-3-(2-acetoxy-ethyl)-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

There total 8 articles about 3-[(1S,3R,4S,5R)-5-Acetoxy-3-(2-acetoxy-ethyl)-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.2%

: 123886-94-2
3-[(1S,3R,4S,5R)-5-Acetoxy-2,2,4-trimethyl-3-(3-oxo-butyl)-cyclohexyl]-propionic acid ethyl ester

: 123886-99-7
3-[(1S,3R,4S,5R)-5-Acetoxy-3-(2-acetoxy-ethyl)-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In 1,2-dichloro-ethane; at 55 ℃; for 44h;
DOI:10.1248/cpb.36.4722

Reference yield:

: 123886-93-1
ethyl 3-(5α-hydroxy-2,2,4α-trimethyl-3α-(3-oxobutyl)cyclohexan-1α-yl)propionate

: 123886-99-7
3-[(1S,3R,4S,5R)-5-Acetoxy-3-(2-acetoxy-ethyl)-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / pyridine / 4 h / Ambient temperature

2: 91.2 percent / mCPBA / 1,2-dichloro-ethane / 44 h / 55 °C

With 3-chloro-benzenecarboperoxoic acid; In pyridine; 1,2-dichloro-ethane;
DOI:10.1248/cpb.36.4722

Reference yield:

: 123886-91-9
{(1S,3R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2,2,4-trimethyl-3-[2-(2-methyl-[1,3]dioxolan-2-yl)-ethyl]-cyclohexyl}-methanol

: 123886-99-7
3-[(1S,3R,4S,5R)-5-Acetoxy-3-(2-acetoxy-ethyl)-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 1.35 g / AcONa*3H₂O, PCC / CH₂Cl₂ / 2.5 h / Ambient temperature

2: toluene / 16 h / 100 °C

3: 851 mg / PtO₂/hydrogen / ethyl acetate / 0.5 h / Ambient temperature

4: 1.) p-toluenesulfonic acid / 1.) acetone, rt., 5 h; 2.) EtOH, 50 deg C, 5 h

5: 100 percent / pyridine / 4 h / Ambient temperature

6: 91.2 percent / mCPBA / 1,2-dichloro-ethane / 44 h / 55 °C

With platinum(IV) oxide; hydrogen; sodium acetate; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; In pyridine; dichloromethane; ethyl acetate; 1,2-dichloro-ethane; toluene;
DOI:10.1248/cpb.36.4722