Tetrachloro(2,2-dimethyl-1,3-propanediamine-N,N')platinum

Base Information

• Chemical Name: Tetrachloro(2,2-dimethyl-1,3-propanediamine-N,N')platinum
• CAS No.: 72968-10-6
• Molecular Formula: C₅H₁₄Cl₄N₂Pt
• Molecular Weight: 439.072
• Mol file: 72968-10-6.mol

Synonyms:cis-platinum-2,2-dimethyl-1,3-diaminopropane tetrachloride;cis-Pt(2,2-dimethyl-1,3-diaminopropane)tetrachloride;Pt(IV)(DMDAP)Cl4;tetrachloro(2,2-dimethyl-1,3-propanediamine-N,N')platinum

Chemical Property of Tetrachloro(2,2-dimethyl-1,3-propanediamine-N,N')platinum

Chemical Property:

• Boiling Point: 150.4oC at 760 mmHg
• Flash Point: 47.2oC
• PSA: 24.06000
• LogP: 3.53350
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 438.952953
• Heavy Atom Count: 12
• Complexity: 63.2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(CN)CN.Cl[Pt-2](Cl)(Cl)Cl

Technology Process of Tetrachloro(2,2-dimethyl-1,3-propanediamine-N,N')platinum

There total 3 articles about Tetrachloro(2,2-dimethyl-1,3-propanediamine-N,N')platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-Pt(Me2tn)Cl2 (28866-75-3) → tetrachloro(2,2-dimethyl-1,3-propanediamine)platinum(IV) (72968-10-6)

Guidance literature:

With HCl; H₂O₂; In water; Pt-compd., 2 N HCl and 30 % H2O2 boiled; the soln. cooled, the product filtered, washed with ethanol/water, ethanol, diethyl ether, dried in vac. at room temp.; elem. anal.;

DOI:10.1021/ic50208a011

Reference yield:

diiodo(2,2-dimethyl-1,3-propanediamine-κ2N,N')platinum(II) (72968-08-2) → tetrachloro(2,2-dimethyl-1,3-propanediamine)platinum(IV) (72968-10-6)

Guidance literature:

Multi-step reaction with 2 steps

1: NaNO₃; AgNO₃ / acetone; water

2: HCl; H₂O₂ / water

With NaNO₃; AgNO₃; HCl; H₂O₂; In water; acetone;

DOI:10.1021/ic50208a011

Reference yield:

2,2-Dimethyl-1,3-diaminopropane (7328-91-8) → tetrachloro(2,2-dimethyl-1,3-propanediamine)platinum(IV) (72968-10-6)

Guidance literature:

Multi-step reaction with 3 steps

1: water

2: NaNO₃; AgNO₃ / acetone; water

3: HCl; H₂O₂ / water

With NaNO₃; AgNO₃; HCl; H₂O₂; In water; acetone;

DOI:10.1021/ic50208a011

upstream raw materials:

cis-Pt(Me₂tn)Cl₂

diiodo(2,2-dimethyl-1,3-propanediamine-κ2N,N')platinum(II)

2,2-Dimethyl-1,3-diaminopropane

Refernces